Synthesis and Characterization of Fluorinated Hypervalent Tellurium Derivatives
作者： Ewa Pietrasiak , Antonio Togni
DOI: 10.1021/ACS.ORGANOMET.7B00535
关键词: Polymer chemistry 、 Chemistry 、 Trimethylsilyl 、 Organic chemistry 、 Hypervalent molecule 、 Characterization (materials science) 、 Tellurium
摘要: The synthesis of tellurium derivatives bearing fluorinated groups, similar in structure to their hypervalent iodine congeners, is reported. Thus, a series CF3, CF2H, and C6F5 aryltellurium(II) species various functional groups interacting with the Te atom was obtained. installation relies on use corresponding trimethylsilyl precursors. nature products discussed basis NMR spectroscopic X-ray crystallographic characterization.
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