Synthesis and reactions of a thiocarbonyl-bridged complex, dicarbonylbis([eta]-cyclopentadienyl)-[mu]-carbonyl-[mu]-thiocarbonyldiiron

摘要: s a sulfur atom from the IT-CŜ intermediate, and MeOH are both necessary for maximum yields. The reaction works poorly with IrCl(PPĥ ) , however, Kubota Careŷ found trans»IrCl(PPĥ )) to be superior starting material preparation of iridium analog# CŜ /'PPhĵ has been used in synthesis several other metal thiocarbonyls# Butler co-workerŝ * obtained CpM(C0)2CS (M = Mn, Be) by sequence 2 (where L cis-cvclooctene or THF)# Repetition this