Facile thermodynamic conversion of a linear metallopolymer into a self-assembled hexameric metallomacrocycle
作者： Yiming Li , Zhilong Jiang , Jie Yuan , Die Liu , Tun Wu
DOI: 10.1039/C4CC10361K
关键词: Stereochemistry 、 Crystallography 、 Chemistry 、 Self assembled
摘要: The initial metallopolymer, derived from two different organic building blocks, is a kinetic intermediate to the final stable hexanuclear (bearing 4Ru2+ and 2Fe2+) metallomacrocycle obtained through thermodynamic dis-assembly/re-assembly route. heteroleptic metallomacrocyclic architecture was characterized by NMR, UV, IR, CV, 2D-ROESY, DOSY, ESI-MS.
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