Electrodeposition of Cu – Al2O3 Thin Films and Microposts in Ammonia-Citrate Electrolytes

作者: A. Lozano-Morales , J. Fitzgerald , V. Singh , X. Xie , E. J. Podlaha

DOI: 10.1149/1.2207840

关键词: Thin filmPartial currentElectrolyteReaction rateComposite numberMetallurgyElectrodeChemical engineeringNanocompositeRotating disk electrodeMaterials science

摘要: The electrodeposition of Cu-γ-Al 2 O 3 nanocomposites as thin films and into recessed electrodes prepared with X-ray lithography was examined in ammonia-citrate electrolytes. Partial current density, efficiency deposit particle concentration were determined a rotating disk electrode. At pH 8 the presence particles resulted an enhancement Cu reaction rate, while at 10 rate appeared inhibited. amount larger for than 10, rendering solution more promising electrolyte to electrodeposit 500 μm deep recesses MEMS composite components.

参考文章(42)
M. H. Fawzy, M. M. Ashour, A. M. Abd El-Halim, Effect of some operating variables on the characteristics of electrodeposited Ni-α-Al2O3 and Ni-TiO2 composites Transactions of The Institute of Metal Finishing. ,vol. 73, pp. 132- 138 ,(1995) , 10.1080/00202967.1995.11871075
Jean L. Stojak, Jan B. Talbot, Effect of particles on Polarization during Electrocodeposition using a Rotating Cylinder Electrode Journal of Applied Electrochemistry. ,vol. 31, pp. 559- 564 ,(2001) , 10.1023/A:1017558430864
D. L. Wang, J. Li, Ch. S. Dai, X. G. Hu, An adsorption strength model for the electrochemical codeposition of α-Al2O3 particles and a Fe–P alloy Journal of Applied Electrochemistry. ,vol. 29, pp. 437- 444 ,(1999) , 10.1023/A:1003406117342
Ryszard Sprycha, Electrical double layer at alumina/electrolyte interface: I. Surface charge and zeta potential joint international conference on information sciences. ,vol. 127, pp. 1- 11 ,(1989) , 10.1016/0021-9797(89)90002-7
A. Lozano-Morales, E. J. Podlaha, The Effect of Al2 O 3 Nanopowder on Cu Electrodeposition Journal of The Electrochemical Society. ,vol. 151, ,(2004) , 10.1149/1.1752934
C. Madore, M. Matlosz, D. Landolt, Blocking Inhibitors in Cathodic Leveling I. Theoretical Analysis Journal of The Electrochemical Society. ,vol. 143, pp. 3927- 3936 ,(1996) , 10.1149/1.1837318
D. W. Lee, O. Tolochko, C. J. Choi, B. K. Kim, Aluminium oxide dispersion strengthened copper produced by thermochemical process Powder Metallurgy. ,vol. 45, pp. 267- 270 ,(2002) , 10.1179/003258902225002532
J. Fransaer, J. P. Celis, J. R. Roos, Analysis of the Electrolytic Codeposition of Non‐Brownian Particles with Metals Journal of The Electrochemical Society. ,vol. 139, pp. 413- 425 ,(1992) , 10.1149/1.2069233
E. Chassaing, K. Vu Quang, R. Wiart, Kinetics of copper electrodeposition in citrate electrolytes Journal of Applied Electrochemistry. ,vol. 16, pp. 591- 604 ,(1986) , 10.1007/BF01006854
Erik E Luther, Joesph A. Yanez, George V Franks, Fred F. Lange, Dale S. Pearson, Effect of Ammonium Citrate on the Rheology and Particle Packing of Alumina Slurries Journal of the American Ceramic Society. ,vol. 78, pp. 1495- 1500 ,(1995) , 10.1111/J.1151-2916.1995.TB08843.X