A tetranuclear 3d-4f single molecule magnet: [CuIILTbIII(hfac)2]2.

作者： Shutaro Osa , Takafumi Kido , Naohide Matsumoto , Nazzareno Re , Andrzej Pochaba

关键词: Nuclear magnetic resonance 、 Magnetic susceptibility 、 Crystallography 、 Molecular magnets 、 Single-molecule magnet 、 Magnetic hysteresis 、 Metal ions in aqueous solution 、 Molecule 、 Chemistry 、 Magnetic anisotropy 、 Ground state

摘要: We report now the first single molecule magnet (SMM) consisting of d−f elements. The present study demonstrates that synthesis polynuclear is a very promising approach to SMMs. (1) can be easily synthesized by assembly reaction d-component and f-component, (2) high-spin ground state generated smaller number metal ions than d complex, (3) molecular magnetic anisotropy derived from f-component.