Structural and hydriding–dehydriding properties of Ho1−xTixCo2 alloys

作者: G. Srinivas , V. Sankaranarayanan , S. Ramaprabhu

DOI: 10.1016/J.MSEA.2007.03.039

关键词: HydridePhysical chemistryDiffractionDesorptionMineralogyDifferential scanning calorimetryMaterials scienceLaves phaseThermogravimetryHydrogenInterstitial defectMechanical engineeringGeneral Materials ScienceMechanics of MaterialsCondensed matter physics

摘要: Abstract The influence of Ti on the structural and hydrogen absorption–desorption properties Laves phase Ho 1− x Co 2 (  = 0–0.6) alloys have been studied using X-ray diffraction (XRD), pressure–composition (PC) isotherms, differential scanning calorimetry (DSC) thermogravimetry (TG). crystalline nature lattice expansion hydrogenated at different concentrations reported. In addition, coexistence two hydride phases intermediate has identified from XRD. changes in plateau pressure capacity upon increasing content discussed. preferential occupation types interstitial sites DSC studies hydrides. complete desorption temperature obtained TG

参考文章(34)
K. Aoki, X-G. Li, T. Masumoto, Differential thermal analysis of hydrogen-induced amorphization in C15 laves phase GdFe2 Acta Metallurgica Et Materialia. ,vol. 40, pp. 221- 227 ,(1992) , 10.1016/0956-7151(92)90297-R
I.Yu. Zavaliy, R. C̆erný, V.N. Verbetsky, R.V. Denys, A.B. Riabov, Interaction of hydrogen with RECu2 and RE(Cu,Ni)2 intermetallic compounds (RE=Y, Pr, Dy, Ho)☆ Journal of Alloys and Compounds. ,vol. 358, pp. 146- 151 ,(2003) , 10.1016/S0925-8388(03)00067-7
M. Kandavel, S. Ramaprabhu, Hydriding properties of Ti-substituted non-stoichiometric AB2 alloys Journal of Alloys and Compounds. ,vol. 381, pp. 140- 150 ,(2004) , 10.1016/J.JALLCOM.2004.03.081
T.R. Kesavan, R. Ramesh, K.V.S. Rama Rao, Hydrogen absorption studies in Zr0.4Ho0.6Fe2 Journal of Alloys and Compounds. ,vol. 226, pp. 46- 50 ,(1995) , 10.1016/0925-8388(95)01580-9
Huang Taizhong, Wu Zhu, Xia Baojia, Huang Tiesheng, Influence of V content on structure and hydrogen desorption performance of TiCrV-based hydrogen storage alloys Materials Chemistry and Physics. ,vol. 93, pp. 544- 547 ,(2005) , 10.1016/J.MATCHEMPHYS.2005.04.004
P. Spatz, K.J. Gross, A. Züttel, L. Schiapbach, Hydriding properties of Ce(Mn, Al)(2) and Ce(Fe, Al)(2) intermetallic compounds Journal of Alloys and Compounds. ,vol. 260, pp. 211- 216 ,(1997) , 10.1016/S0925-8388(97)00133-3
C. E. Krill, J. Li, W. B. Yelon, W. L. Johnson, Search for instability-induced amorphization in deuterated ErFe2. Physical Review B. ,vol. 48, pp. 3689- 3697 ,(1993) , 10.1103/PHYSREVB.48.3689
Taizhong Huang, Zhu Wu, Baojia Xia, Jinzhou Chen, Xuebin Yu, Naixin Xu, Changwei Lu, Huimei Yu, TiCr1.2(V–Fe)0.6—a novel hydrogen storage alloy with high capacity Science and Technology of Advanced Materials. ,vol. 4, pp. 491- 494 ,(2003) , 10.1016/J.STAM.2003.12.001
X YU, Z YANG, S FENG, Z WU, N XU, Influence of Fe addition on hydrogen storage characteristics of Ti-V-based alloy International Journal of Hydrogen Energy. ,vol. 31, pp. 1176- 1181 ,(2006) , 10.1016/J.IJHYDENE.2005.09.008