Luminescent Ag+ exchanged SOD zeolites with their potential applications in white LEDs.

作者: Decui Yao , Yige Wang , Peng Li , Huanrong Li

DOI: 10.1039/D0DT01425G

关键词: Analytical chemistryPhosphorColor temperatureLight-emitting diodeLuminescenceMicroporous materialColor rendering indexChromaticityExcitationMaterials science

摘要: Ag+ exchanged zeolites (Ag-zeolites) combining the advantages of high stability microporous with unique optical properties silver clusters are attractive as promising functional materials. In this work, we systematically studied SOD zeolites, obtaining tuned emission from yellow to blue and for first time acquired white-emitting Ag-zeolite phosphors at a mild temperature (<300 °C). This tunable color was found be caused by lattice shrinkage expansion framework in zeolites. The obtained white emitting show Commission Internationale de I'Eclairage (CIE) chromaticity coordinates (0.33, 0.34) under 395 nm excitation. addition, fabricated warm LEDs these phosphors, which CIE (0.37, 0.34), lower correlated (CCT) 4329 K higher rendering index (CRI) 91.

参考文章(42)
Eduardo Coutino-Gonzalez, Wouter Baekelant, Didier Grandjean, Maarten B. J. Roeffaers, Eduard Fron, Mohammad S. Aghakhani, Nicolas Bovet, Mark Van der Auweraer, Peter Lievens, Tom Vosch, Bert Sels, Johan Hofkens, Thermally activated LTA(Li)–Ag zeolites with water-responsive photoluminescence properties Journal of Materials Chemistry C. ,vol. 3, pp. 11857- 11867 ,(2015) , 10.1039/C5TC02723C
H. Lin, K. Imakita, M. Fujii, V. Yu. Prokof'ev, N. E. Gordina, B. Saïd, A. Galarneau, Visible emission from Ag+ exchanged SOD zeolites Nanoscale. ,vol. 7, pp. 15665- 15671 ,(2015) , 10.1039/C5NR04246A
Gert De Cremer, Bert F Sels, Jun‐ichi Hotta, Maarten BJ Roeffaers, Evelyne Bartholomeeusen, Eduardo Coutiño‐Gonzalez, Valentin Valtchev, Dirk E De Vos, Tom Vosch, Johan Hofkens, None, Optical Encoding of Silver Zeolite Microcarriers Advanced Materials. ,vol. 22, pp. 957- 960 ,(2010) , 10.1002/ADMA.200902937
Gert De Cremer, Eduardo Coutiño-Gonzalez, Maarten BJ Roeffaers, Bart Moens, Jeroen Ollevier, Mark Van der Auweraer, Robert Schoonheydt, Pierre A Jacobs, Frans C De Schryver, Johan Hofkens, Dirk E De Vos, Bert F Sels, Tom Vosch, None, Characterization of fluorescence in heat-treated silver-exchanged zeolites. Journal of the American Chemical Society. ,vol. 131, pp. 3049- 3056 ,(2009) , 10.1021/JA810071S
D. E. W. Vaughan, H. P. Yennawar, A. J. Perrotta, Synthesis and Structure of Large Optically Clear Crystals of Gallogermanate Sodalite Crystal Growth & Design. ,vol. 6, pp. 2072- 2075 ,(2006) , 10.1021/CG060164C
W. Schulze, G. Ertl, C. Félix, C. Sieber, W. Harbich, J. Buttet, I. Rabin, Fluorescence and excitation spectra of Ag4 in an argon matrix Chemical Physics Letters. ,vol. 313, pp. 105- 109 ,(1999) , 10.1016/S0009-2614(99)01034-9
Hiroshi Sakuma, Katsuyuki Kawamura, Structure and dynamics of water on Li+-, Na+-, K+-, Cs+-, H3O+-exchanged muscovite surfaces: A molecular dynamics study Geochimica et Cosmochimica Acta. ,vol. 75, pp. 63- 81 ,(2011) , 10.1016/J.GCA.2010.10.007
De-Chang Lin, Xiao-Wen Xu, Feng Zuo, Ying-Cai Long, Crystallization of JBW, CAN, SOD and ABW type zeolite from transformation of meta-kaolin Microporous and Mesoporous Materials. ,vol. 70, pp. 63- 70 ,(2004) , 10.1016/J.MICROMESO.2004.03.003
Avelino Corma, Patricia Concepción, Mercedes Boronat, Maria J Sabater, Javier Navas, Miguel José Yacaman, Eduardo Larios, Alvaro Posadas, M Arturo López-Quintela, David Buceta, Ernest Mendoza, Gemma Guilera, Alvaro Mayoral, None, Exceptional oxidation activity with size-controlled supported gold clusters of low atomicity Nature Chemistry. ,vol. 5, pp. 775- 781 ,(2013) , 10.1038/NCHEM.1721
Roland Seifert, Andreas Kunzmann, Gion Calzaferri, The Yellow Color of Silver-Containing Zeolite A Angewandte Chemie International Edition. ,vol. 37, pp. 1521- 1524 ,(1998) , 10.1002/(SICI)1521-3773(19980619)37:11<1521::AID-ANIE1521>3.0.CO;2-V