Fe3O4@mesoporous SBA-15: a robust and magnetically recoverable catalyst for one-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones via the Biginelli reaction.
作者： John Mondal , Tapas Sen , Asim Bhaumik
DOI: 10.1039/C2DT30106G
关键词: Nanoparticle 、 Magnetite 、 Mesoporous material 、 Organic chemistry 、 Chemistry 、 Conjugated system 、 Click chemistry 、 Biginelli reaction 、 Catalysis 、 Nuclear chemistry 、 One-pot synthesis
摘要: A magnetic nanoparticle conjugated mesoporous nanocatalyst (Fe(3)O(4)@mesoporous SBA-15) with a high surface area has been synthesized by chemical conjugation of magnetite (Fe(3)O(4)) nanoparticles functionalized SBA-15. Functionalized SBA-15 containing carboxyl and amino groups was via the thiol-ene click reaction cysteine hydrochloride vinyl The catalytic activity robust, safe magnetically recoverable Fe(3)O(4)@mesoporous evaluated in Biginelli under mild conditions for synthesis diverse range 3,4-dihydropyrimidin-2(1H)-ones. separation reuse were simple, effective economical.
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