Fourier-transform infrared spectra of formaldoxime:ν 4 , ν 5 ,ν 6 , and ν 8 bands

摘要: The infrared spectra of the ν4, ν5,ν6, and ν8 fundamentals formaldoxime, CH2NOH, have been obtained in gas phase at high resolution analyzed detail. region covered is from 5 to 14 μm. Since molecule has Cs symmetry, principle all these bands are AB hybrids, since they belong irreducible representation A′. However, it was found that possess a dominant A component. main results (in inverse centimeters) for excited states these: Bandν0ABCν41639.47762.2438020.3934990.334439ν51410.4772.2649210.3945130.335621ν61318.97702.2633020.39715030.3352193ν8892.58032.2436860.3935160.334506