Synthesis and reactivity of 1,1-disodio-2,3,4,5-tetraphenyl-1-silacyclopentadiene
作者： Wan-Chul Joo , Jang-Hwan Hong , Seok-Bong Choi , Hae-Eun Son , Chang Hwan Kim
DOI: 10.1016/0022-328X(90)80153-Q
关键词: Reactivity (chemistry) 、 Organic chemistry 、 Chemistry 、 Sodium 、 Medicinal chemistry 、 Organic anion
摘要: Abstract 1,1-Disodio-2,3,4,5-tetraphenyl-1-silacyclopentadiene (II, 1,1-disodio-TPSCp) was obtained from the reaction of 1,1-dichloro-2,3,4,5-tetraphenyl-1-silacyclopentadiene (1,1-dichloro-TPSCp) with sodium. The II MeI and XSiMe 2 Cl (X = H, Me, Cl) gave corresponding 1,1-dimethyl-, 1,1-bis(XSiMe )-TPSCp's, respectively. In contrast, Me 3 ECl (E C, Sn) bis(1-Me E-2,3,4,5-tetraphenyl-1-silacyclopentadienyl).
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