Tridentate-Bridged Polyazine Complexes of Ruthenium(ll) and Osmium(ll) and their Application to the Development of Photochemical Molecular Devices
作者： Karen J. Brewer
DOI: 10.1080/02603599908012007
关键词: Chemistry 、 Ruthenium 、 Osmium 、 Chromophore 、 Context (language use) 、 Electron transfer 、 Photochemistry
摘要: Abstract The application of polymetallic complexes to photochemical energy conversion is an active area research. use tridentate within this context has been less well explored than the highly studied trisbidentate structural motif. Recent interest expanded explore class bridged that incorporate RuII and OsII chromophores. These systems hold promise in they give rise are stereochemically defined. This important construction molecular devices utilize or electron transfer as it will allow control donor—acceptor distance orientation. article describes some recent research study polyazine-based, tridentate-bridged containing Ru11 Os11
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