A Highly Substrate-Selective Metal Nanoreactor Using a Template-Imprinted Memory
作者： Xiaohui Liu , Hong Yue , Songjun Li , Wuke Li , None
DOI: 10.1007/S10904-009-9265-9
关键词: Molecular recognition 、 Catalysis 、 Metal 、 Metal nanoparticles 、 Substrate (chemistry) 、 Materials science 、 Nanoparticle 、 Molecular imprinting 、 Nanotechnology 、 Nanoreactor
摘要: The study presents an original, highly substrate-selective nanoreactor. nanoreactor, consisting of a template-imprinted memory and Au nanoparticles, was fabricated using the molecular imprinting 4-nitrophenol (4-NP) ionic precursor. within nanoreactor induced behavior. prepared capable specifically recognizing 4-NP but not its analogues 2-nitrophenol (2-NP) 3-nitrophenol (3-NP). Under comparable conditions significantly accelerated reduction 4-NP; however, only minimal promotion for 2-NP 3-NP arose in presence Unlike traditional nanoreactors short recognition elements, composed substrate-imprinted frameworks, which thereby bred catalysis.
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