Highly selective oxidation of aldonic acids to 2-keto-aldonic acids over Pt—Bi and Pt—Pb catalysts

作者: A. Abbadi , H. van Bekkum

DOI: 10.1016/0926-860X(94)00285-1

关键词: CatalysisChemistryInorganic chemistryChelationPlatinumSelectivityTransition metalAldonic acidHeterogeneous catalysisGluconic acid

摘要: … eliminates the poisoning of the catalyst. The use of the Pt-Pb catalyst for the oxidation of sodium … (pH 8 ) this catalyst exhibited the same failure as the Pt-Bi catalyst in losing its selectivity …

参考文章(14)
K. Heyns, H. Paulsen, G. Rüdiger, J. Weyer, Konfigurations- und Konformationsselektivität bei katalytischen Oxydationen mit Sauerstoff am Platin-Kontakt Organische Chemie. pp. 285- 374 ,(1969) , 10.1007/BFB0050701
William Pascoe, Catalysis of organic reactions M. Dekker. ,(1992)
A. Abbadi, M. Makkee, W. Visscher, J. A. R. van Veen, H. van Bekkum, Effect of pH in the Pd-Catalyzed Oxidation of D-Glucose to D-Gluconic Acid Journal of Carbohydrate Chemistry. ,vol. 12, pp. 573- 587 ,(1993) , 10.1080/07328309308019408
Donald T. Sawyer, James R. Brannan, Proton Nuclear Magnetic Resonance Studies of Metal Gluconate Complexes. I. Lead(II) and Bismuth(III) Inorganic Chemistry. ,vol. 5, pp. 65- 70 ,(1966) , 10.1021/IC50035A016
Donald T. Sawyer, Metal-Gluconate Complexes Chemical Reviews. ,vol. 64, pp. 633- 643 ,(1964) , 10.1021/CR60232A003
Peter Klüfers, Jörg Schuhmacher, Sechzehnfach deprotonierte γ-Cyclodextrin-Tori als Anionen in einem sechzehnkernigen Blei(II)-alkoxid Angewandte Chemie. ,vol. 106, pp. 1925- 1927 ,(1994) , 10.1002/ANGE.19941061811