Mild oxidative cleavage of alkynes using [bis(trifluoroacetoxy)iodo]pentafluorobenzene

作者： Robert M. Moriarty , Raju Penmasta , Alok K. Awasthi , Indra Prakash

关键词: Oxidative cleavage 、 Chemistry 、 Medicinal chemistry

摘要: … A possible mechanistic pathway is presented in Scheme III for both terminal and internal alkynes. Initial electrophilic addition of (i) to the alkyne yields A followed by capture of the vinyl …