Kinetics and Mechanism of Addition of Benzylamines to Methyl α-Cyanocinnamates in Acetonitrile
作者：
DOI: 10.5012/BKCS.2009.30.8.1887
关键词: Amine gas treating 、 Substituent 、 Medicinal chemistry 、 Aqueous solution 、 Mechanism (philosophy) 、 Kinetics 、 Chemistry 、 Acetonitrile 、 Nucleophile 、 Photochemistry
摘要: [BA] (5)Studies of substituent effects on the reactions amine nucleophiles with olefins which are activated by electron- acceptors, Z and Z' in eq 1, have shown important difference mechanism between aqueous solution acetonitrile. In solution, were found to proceed through a zwitterionic intermediate, T
koreascience.or.kr参考文章(17)
Kinetics and Mechanism of the Addition of Benzylamines to Benzylidene Meldrum's Acids in Acetonitrile Bulletin of The Korean Chemical Society. ,vol. 24, pp. 193- 196 ,(2003) , 10.5012/BKCS.2003.24.2.193
Kinetics and Mechanism of the Addition of Benzylamines to α-Cyano-β-phenylacrylamides in Acetonitrile Bulletin of The Korean Chemical Society. ,vol. 26, pp. 935- 938 ,(2005) , 10.5012/BKCS.2005.26.6.935
Kinetics and Mechanism of the Addition of Benzylamines to Ethyl-α-cyanocinnamates in Acetonitrile Bulletin of The Korean Chemical Society. ,vol. 23, pp. 221- 224 ,(2002) , 10.5012/BKCS.2002.23.2.221
Michael I. Page, Andrew Williams, Organic and Bio-Organic Mechanisms ,(1997)
Ikchoon Lee, Chang Kon Kim, In Suk Han, Hai Whang Lee, Wang Ki Kim, Yong Bin Kim, THEORETICAL STUDIES OF SOLVENT EFFECT ON THE BASICITY OF SUBSTITUTED PYRIDINES Journal of Physical Chemistry B. ,vol. 103, pp. 7302- 7307 ,(1999) , 10.1021/JP991115W
Claude F. Bernasconi, Nucleophilic addition to olefins. Kinetics and mechanism Tetrahedron. ,vol. 45, pp. 4017- 4090 ,(1989) , 10.1016/S0040-4020(01)81304-1
Ikchoon Lee, SECONDARY KINETIC ISOTOPE EFFECTS INVOLVING DEUTERATED NUCLEOPHILES Chemical Society Reviews. ,vol. 24, pp. 223- 229 ,(1995) , 10.1039/CS9952400223
Claude F. Bernasconi, Intrinsic barriers of reactions and the principle of nonperfect synchronization Accounts of Chemical Research. ,vol. 20, pp. 301- 308 ,(1987) , 10.1021/AR00140A006
Claude F. Bernasconi, Rodney J. Ketner, Kinetics of the Reactions of Benzylidene Meldrum's Acid with Thiolate and Alkoxide Ions in Aqueous Dimethyl Sulfoxide Journal of Organic Chemistry. ,vol. 63, pp. 6266- 6272 ,(1998) , 10.1021/JO980574A
Hyuck Keun Oh, In Kon Kim, Hai Whang Lee, Ikchoon Lee, Kinetics and mechanism of the addition of benzylamines to benzylidenediethylmalonates in acetonitrile. Journal of Organic Chemistry. ,vol. 69, pp. 3806- 3810 ,(2004) , 10.1021/JO034370S