Raman linewidth study of rotational motion of benzene in aqueous solution

作者: Kazutoshi Tanabe

DOI: 10.1016/0584-8539(82)80185-2

关键词: BenzeneViscosityAnalytical chemistryChemistryLaser linewidthRotational diffusionIsotropyAqueous solutionRaman spectroscopyAnisotropyPhotochemistry

摘要: Abstract Linewidths of isotropic and anisotropic Raman bands the ν 2 mode benzene at 991 cm −1 are measured in H O, CS CCl 4 solutions neat liquid. A correlation is examined between viscosity medium rotational diffusion constant determined from linewidths, effect hydrophobic hydration on motion molecules discussed.

参考文章(5)
W. Kauzmann, Some factors in the interpretation of protein denaturation. Advances in Protein Chemistry. ,vol. 14, pp. 1- 63 ,(1959) , 10.1016/S0065-3233(08)60608-7
D. W. Davidson, J. A. Ripmeester, Clathrate Ices—Recent Results Journal of Glaciology. ,vol. 21, pp. 33- 49 ,(1978) , 10.3189/S0022143000033281
Kazutoshi Tanabe, Jiro Hiraishi, Correction of finite slit width effects on Raman line widths Spectrochimica Acta Part A: Molecular Spectroscopy. ,vol. 36, pp. 341- 344 ,(1980) , 10.1016/0584-8539(80)80141-3
Kazutoshi Tanabe, Jiro Hiraishi, Raman study of vibrational and reorientational relaxation of chloroform in solution Advances in Molecular Relaxation and Interaction Processes. ,vol. 16, pp. 281- 297 ,(1980) , 10.1016/0378-4487(80)80017-3