Application of electrochemically produced and oxidized poly(3,4-ethylenedioxythiophene) as anticorrosive additive for paints: Influence of the doping level
作者： Francisco Liesa , Cintia Ocampo , Carlos Alemán , Elaine Armelin , Ramón Oliver
DOI: 10.1002/APP.23925
关键词: Corrosion 、 PEDOT:PSS 、 Chronoamperometry 、 Composite material 、 Epoxy 、 Poly(3,4-ethylenedioxythiophene) 、 Chemical engineering 、 Polymer 、 Conductive polymer 、 Coating 、 Materials science
摘要: This work investigates the resistance against marine corrosion of an epoxy-based coating modified by addition electrochemically produced and oxidized poly(3,4-ethylenedioxythiophene) (PEDOT). For this purpose, electrodeposition PEDOT was performed on steel electrodes electrochemical polymerization 3,4-ethylenedioxythiophene. The doping level resulting material increased chronoamperometry chronopotentiometry (CP), three different oxidation degrees being achieved. electrical properties such samples, which were used as anticorrosive additives, examined. Furthermore, physical before after conducting polymers characterized using FTIR, thermal analyses, mechanical evaluations. Accelerated tests indicated that polymer with highest amount positive charge per monomeric unit, achieved CP, enhances considerably protection imparted coating. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1592–1599,
sci-hub.se 参考文章(22)
A Sezai Saraç, G Sönmez, FC Cebeci, Electrochemical synthesis and structural studies of polypyrroles, poly(3,4-ethylene- dioxythiophene)s and copolymers of pyrrole and 3,4-ethylenedioxythiophene on carbon fibre microelectrodes Journal of Applied Electrochemistry. ,vol. 33, pp. 295- 301 ,(2003) , 10.1023/A:1024139303585
Yen Wei, Jianguo Wang, Xinru Jia, Jui-Ming Yeh, Peter Spellane, Polyaniline as corrosion protection coatings on cold rolled steel Polymer. ,vol. 36, pp. 4535- 4537 ,(1995) , 10.1016/0032-3861(95)96866-7
L. Groenendaal, F. Jonas, D. Freitag, H. Pielartzik, J. R. Reynolds, Poly(3,4‐ethylenedioxythiophene) and Its Derivatives: Past, Present, and Future Advanced Materials. ,vol. 12, pp. 481- 494 ,(2000) , 10.1002/(SICI)1521-4095(200004)12:7<481::AID-ADMA481>3.0.CO;2-C
F. Beck, R. Michaelis, F. Schloten, B. Zinger, Filmforming electropolymerization of pyrrole on iron in aqueous oxalic acid Electrochimica Acta. ,vol. 39, pp. 229- 234 ,(1994) , 10.1016/0013-4686(94)80058-8
Qibing Pei, Guido Zuccarello, Markus Ahlskog, Olle Inganäs, Electrochromic and highly stable poly(3,4-ethylenedioxythiophene) switches between opaque blue-black and transparent sky blue Polymer. ,vol. 35, pp. 1347- 1351 ,(1994) , 10.1016/0032-3861(94)90332-8
José Ignacio Iribarren Laco, Francisco Cadena Villota, Francisco Liesa Mestres, Corrosion protection of carbon steel with thermoplastic coatings and alkyd resins containing polyaniline as conductive polymer Progress in Organic Coatings. ,vol. 52, pp. 151- 160 ,(2005) , 10.1016/J.PORGCOAT.2004.10.005
Berhard Wessling, Passivation of metals by coating with polyaniline: Corrosion potential shift and morphological changes Advanced Materials. ,vol. 6, pp. 226- 228 ,(1994) , 10.1002/ADMA.19940060309
S. Timpanaro, M. Kemerink, F.J. Touwslager, M.M. De Kok, S. Schrader, Morphology and conductivity of PEDOT/PSS films studied by scanning-tunneling microscopy Chemical Physics Letters. ,vol. 394, pp. 339- 343 ,(2004) , 10.1016/J.CPLETT.2004.07.035
Cintia Ocampo, Elaine Armelin, Francisco Liesa, Carlos Alemán, Xavier Ramis, José Ignacio Iribarren, Application of a polythiophene derivative as anticorrosive additive for paints Progress in Organic Coatings. ,vol. 53, pp. 217- 224 ,(2005) , 10.1016/J.PORGCOAT.2005.02.009
Friedrich Jonas, Werner Krafft, Bavo Muys, Poly(3, 4-ethylenedioxythiophene): Conductive coatings, technical applications and properties Macromolecular Symposia. ,vol. 100, pp. 169- 173 ,(1995) , 10.1002/MASY.19951000128