Some Aspects of Vitrification, Amorphisation and Disordering and the Generated Extent of Nano-Crystallinity

作者: Jaroslav Šesták , Carlos A. Queiroz , Jiří J. Mareš , Miroslav Holeček

DOI: 10.1007/978-90-481-2882-2_4

关键词: Raw materialAmorphous metalChemical engineeringNano-MeteoriteAmorphous solidQuenchingCrystallinityMaterials scienceVitrification

摘要: Historically, glass is often viewed as a remarkable translucent substance though usually made from the simplest raw materials upon effect of firing. Nature, itself, best instance to learn how different temperature changes can provide various glassy states, altering very slow rates occurring within geological time scales (e.g. obsidians – volcanic rocks consisting natural acidic silicate glasses) extremely fast, result fast energetically driven collapse (e.g., by impact meteorites, yielding melted droplets then cooled tektites). Mimicking evolution, however, man became responsible for creation further families wide variety and amorphous (geopolymers), which have gradually appeared through human creativity, particularly during last 100 years. Properly chosen procedure rapid extraction heat (often called quenching) turned up be efficient route successful glass-formation (vitrification, repeatable process) almost all substances (thus allowing preparation glasses sorts inorganic materials, including metals) in contrast traditional chemical approach, seeking just an appropriate composition vitrify under customary self-cooling [1,2].

参考文章(60)
Hellmut Fritzsche, What are Non-Crystalline Semiconductors Springer, Berlin, Heidelberg. pp. 1- 13 ,(1981) , 10.1007/978-3-642-81604-8_1
EMILIA ILLEKOVA, I MAT’KO, P DUHAJ, FRANCE-ANNE KUHNAST, The complex characteristics of crystallization of the Fe75Si15B10 glassy ribbon Journal of Materials Science. ,vol. 32, pp. 4645- 4654 ,(1997) , 10.1023/A:1018650107554
Jaroslav Šesták, Heat, thermal analysis and society. Nucleus HK. ,(2004)
Heino Sieber, Gerhard Wilde, Alexander Sagel, John H. Perepezko, Solid State Amorphization by Cold-Rolling Materials Development and Processing - Bulk Amorphous Materials, Undercooling and Powder Metallurgy. pp. 1- 9 ,(2006) , 10.1002/3527607277.CH1
D.R. MacFarlane, M. Matecki, M. Poulain, Crystallization in fluoride glasses Journal of Non-Crystalline Solids. ,vol. 64, pp. 351- 362 ,(1984) , 10.1016/0022-3093(84)90188-1
John M. Hutchinson, Determination of the glass transition temperature: methods correlation and structural heterogeneity Journal of Thermal Analysis and Calorimetry. ,vol. 98, pp. 579- 589 ,(2009) , 10.1007/S10973-009-0268-0