Frequency and atomic mass based selective electrochemical recovery of rare earth metals and isotopes

作者: Prashant K. Sarswat , Michael L. Free

DOI: 10.1016/J.ELECTACTA.2016.10.011

关键词: Atomic massIonic bondingMetalElectronMass distributionDispersion (chemistry)Atomic physicsChemistryLanthanideValence electron

摘要: Abstract Rare earth metals (REMs or lanthanides) are highly useful in applications such as gas sensors, hybrid vehicles, defense equipment, fluorescent and LED lights, metal alloys, well the production of electrical assemblies associated magnets. The energy 4f electrons lanthanides is relatively less than that outer valence electrons. In other words these localized part ionic core. addition, do not directly participate compound forming processes. This a main cause for difficulty chemically separating similar lanthanides. One possible separation technique utilizes effect atomic mass based dispersion, involves application potential with different oscillating frequencies. At lower frequency, range distribution REMs deposited greater at higher frequency. this paper, we present step-by step approach formulation to electrochemically separate REMs.

参考文章(37)
Abner Brenner, Electrodeposition of alloys : principles and practice Academic Press. ,(1963)
Jacques Lucas, Pierre Lucas, Thierry Le Mercier, Alain Rollat, William G Davenport, Rare Earths: Science, Technology, Production and Use ,(2014)
Norimiki Usuzaka, Hiroyuki Yamaguchi, Tohru Watanabe, Preparation and magnetic properties of CoGd amorphous alloy films by the electroplating method Materials Science and Engineering. ,vol. 99, pp. 105- 108 ,(1988) , 10.1016/0025-5416(88)90302-3
Aphichart Rodchanarowan, Prashant K. Sarswat, Ravindra Bhide, Michael L. Free, Production of copper from minerals through controlled and sustainable electrochemistry Electrochimica Acta. ,vol. 140, pp. 447- 456 ,(2014) , 10.1016/J.ELECTACTA.2014.07.015
M. Gibilaro, L. Massot, P. Chamelot, P. Taxil, Study of neodymium extraction in molten fluorides by electrochemical co-reduction with aluminium Journal of Nuclear Materials. ,vol. 382, pp. 39- 45 ,(2008) , 10.1016/J.JNUCMAT.2008.09.004
Kai-Guo Chang, Min-Shou Zhao, Co-deposition of lithium with rare earth from molten chlorides Chinese Journal of Chemistry. ,vol. 9, pp. 27- 33 ,(2010) , 10.1002/CJOC.19910090104
M. Schwartz, N. V. Myung, K. Nobe, Electrodeposition of Iron Group-Rare Earth Alloys from Aqueous Media Journal of The Electrochemical Society. ,vol. 151, ,(2004) , 10.1149/1.1751196
Yuichi Sato, Hiroshi Ishida, Koichi Kobayakawa, Yuki Abe, Electrodeposition of Sm–Co from Formamide Solution Chemistry Letters. ,vol. 19, pp. 1471- 1474 ,(1990) , 10.1246/CL.1990.1471