Zeolites as Partial Oxygenation Catalysts
作者： D.R.C. Huybrechts , R.F. Parton , P.A. Jacobs
DOI: 10.1016/S0167-2991(08)61902-3
关键词: Oxygen 、 Organic chemistry 、 Wacker process 、 Transition metal 、 Hydroxylation 、 Catalysis 、 Furan 、 Zeolite 、 Chemistry 、 Maleic anhydride
摘要: The use of zeolite catalysts for partial oxygenations organic substrates with dioxygen or peroxidic oxygen sources is reviewed. Oxidative properties were introduced in zeolites by incorporation transition metals, either as charge neutralizing lattice cations, supported oxides, encaged organometallic complexes. Catalyzed reactions include the oxyfunctionalization alkanes, epoxidation Wacker oxidation alkenes, butadiene to furan maleic anhydride and hydroxylation aromatics.
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