Recent Progress in the Chemistry of Fluorophosphines

作者: John F. Nixon

DOI: 10.1016/S0065-2792(08)60337-4

关键词: Computational chemistryChemistryOrganic chemistry

摘要: Publisher Summary Fluorophosphines are tervalent phosphorus compounds containing phosphorus-fluorine bonds and they often show markedly different chemical behavior compared with other halogenophosphines. This article is mainly concerned recent advances in the chemistry of derivatives PF, type PF3-nXa, particular reference to (a) synthesis new structural types, ( b ) role fluorophosphines as ligands, particularly, transition metal complexes, c nuclear magnetic resonance (NMR) studies.Since form part a general review fluorides (282), there an excellent account metaltrifluorophosphine present not intended be comprehensive, but rather highlight some more developments this expanding area inorganic chemistry.

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