作者: John F. Nixon
DOI: 10.1016/S0065-2792(08)60337-4
关键词: Computational chemistry 、 Chemistry 、 Organic chemistry
摘要: Publisher Summary Fluorophosphines are tervalent phosphorus compounds containing phosphorus-fluorine bonds and they often show markedly different chemical behavior compared with other halogenophosphines. This article is mainly concerned recent advances in the chemistry of derivatives PF, type PF3-nXa, particular reference to (a) synthesis new structural types, ( b ) role fluorophosphines as ligands, particularly, transition metal complexes, c nuclear magnetic resonance (NMR) studies.Since form part a general review fluorides (282), there an excellent account metaltrifluorophosphine present not intended be comprehensive, but rather highlight some more developments this expanding area inorganic chemistry.