Preparation of TiO2 photocatalyst film and its catalytic performance for 1,1′-dimethyl-4,4′-bipyidium dichloride decomposition

作者: Misook Kang

DOI: 10.1016/S0926-3373(01)00303-4

关键词: CoatingParticle sizeCatalysisHydrothermal circulationPhotocatalysisThin filmInorganic chemistryAnataseTitaniumMaterials scienceChemical engineering

摘要: A pure TiO2 colloidal solution for a catalyst with high photocatalytic activity was obtained by thermal hydrolysis of titanium tetra-iso-propoxide (TTIP). The film on pyrex plate, which dip-coated the solution, characterized XRD and SEM analyses. It confirmed that exhibited uniform anatase structure particle size <45 nm thickness about 200 nm in one-time coating. To investigate performance 1,1′-dimethyl-4,4′-bipyidium dichloride (Paraquat) destruction, directly fixed UV-lamp dip-coating method. conversion Paraquat remarkably increased prepared hydrothermal method compared sol–gel method; particular, reached above 95% after 15 h. In addition, stably attached surface reaction. But partially taken off surface. Therefore, this study, it very reliable synthesis thin catalytic performance.

参考文章(17)
Paola Calza, Claudio Minero, Ezio Pelizzetti, Photocatalytically Assisted Hydrolysis of Chlorinated Methanes under Anaerobic Conditions Environmental Science & Technology. ,vol. 31, pp. 2198- 2203 ,(1997) , 10.1021/ES960660X
Iis Sopyan, Mitsuru Watanabe, Sadao Murasawa, Kazuhito Hashimoto, Akira Fujishima, An efficient TiO2 thin-film photocatalyst: photocatalytic properties in gas-phase acetaldehyde degradation Journal of Photochemistry and Photobiology A-chemistry. ,vol. 98, pp. 79- 86 ,(1996) , 10.1016/1010-6030(96)04328-6
Xiaojing Li, Jerry W. Cubbage, Troy A. Tetzlaff, William S. Jenks, Photocatalytic Degradation of 4-Chlorophenol. 1. The Hydroquinone Pathway Journal of Organic Chemistry. ,vol. 64, pp. 8509- 8524 ,(1999) , 10.1021/JO990820Y
Chung-Hsuang Hung, Benito J. Mariñas, Role of Water in the Photocatalytic Degradation of Trichloroethylene Vapor on TiO2 Films Environmental Science & Technology. ,vol. 31, pp. 1440- 1445 ,(1997) , 10.1021/ES960685W
Tetsuro Noguchi, Akira Fujishima, Phillip Sawunyama, Kazuhito Hashimoto, Photocatalytic Degradation of Gaseous Formaldehyde Using TiO2 Film Environmental Science & Technology. ,vol. 32, pp. 3831- 3833 ,(1998) , 10.1021/ES980299+
K. Tennakone, I.R.M. Kottegoda, Photocatalytic mineralization of paraquat dissolved in water by TiO2 supported on polythene and polypropylene films Journal of Photochemistry and Photobiology A-chemistry. ,vol. 93, pp. 79- 81 ,(1996) , 10.1016/1010-6030(95)04141-9
Suzuko Yamazaki-Nishida, Xianzhi Fu, Marc A. Anderson, Kenzi Hori, Chlorinated byproducts from the photoassisted catalytic oxidation of trichloroethylene and tetrachloroethylene in the gas phase using porous TiO2 pellets Journal of Photochemistry and Photobiology A-chemistry. ,vol. 97, pp. 175- 179 ,(1996) , 10.1016/1010-6030(96)04320-1
Suzuko Yamazaki, Satoru Tanaka, Hidekazu Tsukamoto, Kinetic studies of oxidation of ethylene over a TiO2 photocatalyst Journal of Photochemistry and Photobiology A-chemistry. ,vol. 121, pp. 55- 61 ,(1999) , 10.1016/S1010-6030(98)00448-1