Synthesis, characterization and solid state molecular structures of five- and six-coordinate primary amide manganese porphyrin complexes
作者： Nan Xu , Alexander W. Bevak , Bernadette R. Armstrong , Douglas R. Powell
DOI: 10.1016/J.POLY.2016.10.022
关键词: Redox 、 Medicinal chemistry 、 Acetamide 、 Manganese 、 Cationic polymerization 、 Inorganic chemistry 、 Chemistry 、 Cyclic voltammetry 、 Tetra 、 Amide 、 Porphyrin
摘要: Abstract We report the synthesis and characterization of a number primary amide manganese porphyrins from reactions cationic [(por)Mn(THF)2]ClO4 (por = tetraphenylporphyrin dianion (TPP), tetra(p-chlorophenyl) porphyrin (T(p-Cl)PP) [(OEP)Mn]ClO4 (OEP = octaethylporphyrin dianion) precursors with excess acrylamide or acetamide. Two six-coordinate [(por)Mn(O C(NH2)CH CH2)2]ClO4 (por = TPP (1) T(p-Cl)PP (2)) complexes one five-coordinate [(OEP)Mn(O C(NH2)CH3)]ClO4 (4) complex have been structurally characterized by X-ray crystallography. A sole O binding mode ligands in these has determined. The redox behavior studied cyclic voltammetry, showing well-defined reversible reduction couples for both complexes.
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sci-hub.se 参考文章(39)
W. Robert Scheidt, Young Ja Lee, Recent advances in the stereochemistry of metallotetrapyrroles ChemInform. ,vol. 19, pp. 1- 70 ,(1987) , 10.1007/BFB0036789
N.M.N. Gowda, S.B. Naikar, G.K.N. Reddy, Perchlorate Ion Complexes Advances in Inorganic Chemistry. ,vol. 28, pp. 255- 299 ,(1984) , 10.1016/S0898-8838(08)60210-X
Renzo Cini, Francesco P. Intini, Luciana Maresca, Concetta Pacifico, Giovanni Natile, Isomerism of Amides Coordinated to Platinum – X‐ray Crystal Structure of O‐Bonded Acetamide in a Platinum(II) Complex European Journal of Inorganic Chemistry. ,vol. 1998, pp. 1305- 1312 ,(1998) , 10.1002/(SICI)1099-0682(199809)1998:9<1305::AID-EJIC1305>3.0.CO;2-9
George M. Sheldrick, Crystal structure refinement with SHELXL Acta Crystallographica Section C-crystal Structure Communications. ,vol. 71, pp. 3- 8 ,(2015) , 10.1107/S2053229614024218
Robert B. Brown, Michael M. Williamson, Craig L. Hill, Structural and chemical properties of a reactive metalloporphyrin with aliphatic amine N-oxide axial ligands: crystal and molecular structure of bis(N-methylmorpholine N-oxide)(tetraphenylporphinato)manganese(III) perchlorate Inorganic Chemistry. ,vol. 26, pp. 1602- 1608 ,(1987) , 10.1021/IC00257A027
Xi Hai Mu, Franklin A. Schultz, Methanol bonding to and electron-transfer reactivity of chloro(tetraphenylporphinato)manganese(III) Inorganic Chemistry. ,vol. 31, pp. 3351- 3357 ,(1992) , 10.1021/IC00042A006
E. Bergmark, C.J. Calleman, F.S. He, L.G. Costa, Determination of hemoglobin adducts in humans occupationally exposed to acrylamide. Toxicology and Applied Pharmacology. ,vol. 120, pp. 45- 54 ,(1993) , 10.1006/TAAP.1993.1085
Eden Tareke, Thomas M. Heinze, Gonçalo Gamboa da Costa, Syed Ali, Acrylamide Formed at Physiological Temperature as a Result of Asparagine Oxidation Journal of Agricultural and Food Chemistry. ,vol. 57, pp. 9730- 9733 ,(2009) , 10.1021/JF901812U
M. E. Stone, B. E. Robertson, E. Stanley, Crystal structures of dichlorotetrakis(acetaldoxime)nickel(II) and tetrakis(acetamide)bisaquonickel(II) dichloride Journal of the Chemical Society A: Inorganic, Physical, Theoretical. pp. 3632- 3636 ,(1971) , 10.1039/J19710003632
Hiroshi Hori, Masao Ikeda-Saito, Takashi Yonetani, Electron paramagnetic resonance and spectrophotometric studies of the peroxide compounds of manganese-substituted horseradish peroxidase, cytochrome-c peroxidase and manganese-porphyrin model complexes. Biochimica et Biophysica Acta. ,vol. 912, pp. 74- 81 ,(1987) , 10.1016/0167-4838(87)90249-4