X-Ray Structural Analysis of Trinuclear Cobalt Carbonyl Complex SCo3(CO)9
作者： Wei Gao
DOI: 10.1080/15421406.2014.956402
关键词: X-ray 、 Triclinic crystal system 、 Diffraction 、 Crystal 、 Cobalt 、 Chemistry 、 Crystal structure 、 Single crystal 、 Crystallography 、 van der Waals force
摘要: A trinuclear cobalt carbonyl complex SCo3(CO)9 was characterized by single crystal X-ray diffraction analysis. The crystals are triclinic, space group P-1 with a = 9.4646(9), b 12.944(3), c 13.182(3) A, α 109.57(3), β 107.78(3), γ 97.61(3)°, V 1398.5(5) A3, Z 4, F(000) 892, Dc 2.189 g/cm3, μ 3.706 mm−1, the final R 0.0440, and wR 0.0913. total of 14,299 reflections were collected, which 6539 independent (Rint 0.0789). In packing diagram, van der Waals’ interactions stabilize solid state.
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