Synthesis of S-glycosyl thiophosphates, thiophosphonates and thiophosphinates by the Michaelis–Arbuzov rearrangement of anomeric thiocyanates
作者： Marta Piekutowska , Zbigniew Pakulski
DOI: 10.1016/J.CARRES.2007.12.009
关键词: Chemistry 、 Molecule 、 Anomer 、 Stereoselectivity 、 Glycosyl 、 Stereochemistry 、 Glycosylation 、 Organic chemistry 、 Glycoside 、 Analytical chemistry 、 Biochemistry 、 General Medicine
摘要: Reaction of anomeric thiocyanates with a series O-alkyl or O-trimethylsilyl phosphite, phenylphosphonite and diphenylphosphinite derivatives afforded the corresponding S-glycosyl thiophosphates, thiophosphonates thiophosphinates in good yields. These had been previously applied as glycosyl donors synthesis benzyl glycosides disaccharides excellent stereoselectivity.
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