Synthesis and characterization of [Pb{Se2P(OiPr)2}2]n pseudo polymorphs: polymeric, single source precursor enabling preparation of shape-controlled lead selenide structures.
作者： Wen-Shiang Chang , Yi-Feng Lin , Bijay Sarkar , Yu-Min Chang , Ling-Kang Liu
DOI: 10.1039/B921503D
关键词: Lead selenide 、 Phonon 、 Atom 、 Ethylenediamine 、 Chelation 、 Nanostructure 、 Crystallography 、 Raman spectroscopy 、 Ligand 、 Materials science
摘要: Novel lead pseudo polymorphs supported by diselenophosphate (dsep) ligands, [Pb{Se2P(OiPr)2}2]n (1α and 1β), were synthesized structurally characterized. The two structures differed in the binding modes of dsep ligand. Each repeating unit 1α was composed a atom coordinated one chelating mode other bridging–dangling mode. By contrast, ligands 1β adopted bimetallic-biconnective (μ1-S, μ1-S) pattern. observed is first example this for could be successfully utilized as single source precursor (SSP) growing selenide (PbSe) nanostructures with different shapes via solvothermal process. morphologies as-grown PbSe controlled capping agents, poly(vinyl pyrrolidone) (PVP) ethylenediamine, both bind on {200} plane enhance growth rate direction crystals, resulting formation cubes eight-horned rod dendrites, respectively. Raman spectroscopy to investigate phonon vibration behaviour dendrites. All peaks spectra can attributed longitudinal (LO) transverse (TO) optical
rsc.org
sci-hub.se 参考文章(55)
Wanli Ma, Joseph M Luther, Haimei Zheng, Yue Wu, A Paul Alivisatos, Photovoltaic Devices Employing Ternary PbSxSe1-x Nanocrystals Journal of Materials Science & Technology. ,vol. 33, pp. 418- 423 ,(2017) , 10.1016/J.JMST.2017.01.018
C. W. Liu, Iu-Jie Shang, Chiu-Mine Hung, Ju-Chung Wang, Tai-Chiun Keng, Novel silver diselenophosphate clusters: structures of Ag10(μ10-Se)[Se2P(OEt)2]8 and {Ag[Se2P(OPri)2]}6 Journal of The Chemical Society-dalton Transactions. pp. 1974- 1979 ,(2002) , 10.1039/B111095K
Yi-Feng Lin, Yung-Jung Hsu, Shih-Yuan Lu, Wei-Shan Chiang, One-step formation of core–shell sulfide–oxide nanorod arrays from a single precursor Nanotechnology. ,vol. 17, pp. 4773- 4782 ,(2006) , 10.1088/0957-4484/17/18/040
Heon-Cheol Shin, Meilin Liu, Copper Foam Structures with Highly Porous Nanostructured Walls Chemistry of Materials. ,vol. 16, pp. 5460- 5464 ,(2004) , 10.1021/CM048887B
Y. Liu, S. Zha, M. Liu, Novel Nanostructured Electrodes for Solid Oxide Fuel Cells Fabricated by Combustion Chemical Vapor Deposition (CVD) Advanced Materials. ,vol. 16, pp. 256- 260 ,(2004) , 10.1002/ADMA.200305767
Matthew J. Bierman, Y. K. Albert Lau, Song Jin, Hyperbranched PbS and PbSe nanowires and the effect of hydrogen gas on their synthesis. Nano Letters. ,vol. 7, pp. 2907- 2912 ,(2007) , 10.1021/NL071405L
Ian P. Gray, Heather L. Milton, Alexandra M. Z. Slawin, J. Derek Woollins, Synthesis and structure of [Fc(RO)PS2]- complexes Dalton Transactions. pp. 3450- 3457 ,(2003) , 10.1039/B306387A
T.Y. Ko, C.H. Yang, K. Sun, H.W. Chang, B. Sarkar, C.W. Liu, Electrical and optical properties of a single Sb2Se3 nanorod Central European Journal of Chemistry. ,vol. 7, pp. 197- 204 ,(2009) , 10.2478/S11532-008-0070-Z
Tihana Mirkovic, Margaret A. Hines, P. Sreekumari Nair, Gregory D. Scholes, Single-Source Precursor Route for the Synthesis of EuS Nanocrystals Chemistry of Materials. ,vol. 17, pp. 3451- 3456 ,(2005) , 10.1021/CM048064M
Michel Giffard, Nicolas Mercier, Benoît Gravoueille, Emilie Ripaud, Jerôme Luc, Bouchta Sahraoui, Polymorphism of lead(II) benzenethiolate: a noncentrosymmetric new allotropic form of Pb(SPh)2 CrystEngComm. ,vol. 10, pp. 968- 971 ,(2008) , 10.1039/B803434F