Enantioselective Henry Reaction Catalyzed by CuII Salt and Bipiperidine
作者： Artur Noole , Kristin Lippur , Andrus Metsala , Margus Lopp , Tõnis Kanger
DOI: 10.1021/JO902664V
关键词: Enantioselective synthesis 、 Salt (chemistry) 、 Nitroaldol reaction 、 Chemistry 、 Hydrate 、 Aldol condensation 、 Yield (chemistry) 、 Catalysis 、 Copper(II) acetate 、 Organic chemistry
摘要: A complex derived from the enantiomeric bipiperidine and copper(II) acetate hydrate is an efficient catalyst for enantioselective Henry reaction. The easy availability of both components, mild reaction conditions, high yield, good to excellent enantioselectivity make useful everyday practice.
acs.org
sci-hub.se 参考文章(35)
Kimberly Yearick Spangler, Christian Wolf, Asymmetric copper(I)-catalyzed Henry reaction with an aminoindanol-derived bisoxazolidine ligand. Organic Letters. ,vol. 11, pp. 4724- 4727 ,(2009) , 10.1021/OL9018612
Aurélie Toussaint, Andreas Pfaltz, Asymmetric Henry Reactions Catalyzed by Metal Complexes of Chiral Boron-Bridged Bisoxazoline (borabox) Ligands European Journal of Organic Chemistry. ,vol. 2008, pp. 4591- 4597 ,(2008) , 10.1002/EJOC.200800570
Sermadurai Selvakumar, Dhanasekaran Sivasankaran, Vinod K. Singh, Enantioselective Henry reaction catalyzed by C2-symmetric chiral diamine–copper(II) complex Organic and Biomolecular Chemistry. ,vol. 7, pp. 3156- 3162 ,(2009) , 10.1039/B904254G
David A. Evans, Daniel Seidel, Magnus Rueping, Hon Wai Lam, Jared T. Shaw, C. Wade Downey, A new copper acetate-bis(oxazoline)-catalyzed, enantioselective Henry reaction Journal of the American Chemical Society. ,vol. 125, pp. 12692- 12693 ,(2003) , 10.1021/JA0373871
Joshodeep Boruwa, Naminita Gogoi, Partha Pratim Saikia, Nabin C. Barua, Catalytic asymmetric Henry reaction Tetrahedron-asymmetry. ,vol. 17, pp. 3315- 3326 ,(2006) , 10.1016/J.TETASY.2006.12.005
Takayoshi Arai, Ryuta Takashita, Yoko Endo, Masahiko Watanabe, Akira Yanagisawa, Asymmetric syn-selective Henry reaction catalyzed by the sulfonyldiamine-CuCl-pyridine system. Journal of Organic Chemistry. ,vol. 73, pp. 4903- 4906 ,(2008) , 10.1021/JO800412X
Tõnis Kanger, Marju Laars, Kadri Kriis, Tiiu Kailas, Aleksander-Mati Müürisepp, Tõnis Pehk, Margus Lopp, Anchimeric assistance in the case of vicinal dimesylate : Formation of enantiomeric or meso-bimorpholine Synthesis. ,vol. 2006, pp. 1853- 1857 ,(2006) , 10.1055/S-2006-926469
Mehmet Çolak, Nadir Demirel, None, Enantioselective nitroaldol (Henry) reaction catalyzed by chiral Schiff-base ligands Tetrahedron-asymmetry. ,vol. 19, pp. 635- 639 ,(2008) , 10.1016/J.TETASY.2008.02.005
Marju Laars, Kadri Kriis, Tiiu Kailas, Aleksander-Mati Müürisepp, Tõnis Pehk, Tõnis Kanger, Margus Lopp, Structural constraints for C2-symmetric heterocyclic organocatalysts in asymmetric aldol reactions Tetrahedron: Asymmetry. ,vol. 19, pp. 641- 645 ,(2008) , 10.1016/J.TETASY.2008.02.026
Rafał Kowalczyk, Łukasz Sidorowicz, Jacek Skarżewski, Asymmetric Henry reaction catalyzed by chiral secondary diamine-copper(II) complexes Tetrahedron-asymmetry. ,vol. 19, pp. 2310- 2315 ,(2008) , 10.1016/J.TETASY.2008.09.032