Synthesis of NASICON—A Molecular Precursor-Based Approach
作者： P. Porkodi , V. Yegnaraman , P. Kamaraj , V. Kalyanavalli , D. Jeyakumar
DOI: 10.1021/CM800208K
关键词: Inorganic chemistry 、 Ionic bonding 、 Sodium 、 Fast ion conductor 、 Nano- 、 Fourier transform infrared spectroscopy 、 Nuclear chemistry 、 Conductivity 、 Materials science 、 Yield (chemistry) 、 Hydrolysis
摘要: Phosphosilicate molecular precursor for the synthesis of NASICON, natrium super ionic conductor, Na1+xZr2SixP3−xO12 (x = 1 and 2) has been devised prepared by hydrolysis tetraethoxysilane (TEOS) employing sodium phosphate solution. The was reacted with Zr(OC3H7)4 in ethanol under solvolytic condition to yield nano material NASICON. This annealed at high temperature phase-pure characterized using 31P NMR, FTIR spectral data, powder XRD pattern TG/DTA studies. structure deduced from which indicates presence edge sharing tetrahedral arrangement −O−Si−O−P−O−Si− chain. NASICON TG/DTA, FTIR, TEM, SEM, MAS NMR XRD. conductivity synthesized measured pellet 900 °C found be 5.5 x10−3 S cm−1. details on preliminary inves...
acs.org
csircentral.net
sci-hub.se 参考文章(37)
P. Pasierb, S. Komornicki, R. Gajerski, S. Koziński, P. Tomczyk, M. Rękas, Electrochemical Gas Sensor Materials Studied by Impedance Spectroscopy Part I: Nasicon as a Solid Electrolyte Journal of Electroceramics. ,vol. 8, pp. 49- 55 ,(2002) , 10.1023/A:1015599202914
Lilian Emilia Davies, Norberto Alejandro Bonini, Elio Emilio Gonzo, Silvano Locatelli, Characterization and catalytic activity of zirconium dioxide prepared by sol-gel Latin American Applied Research. ,vol. 35, pp. 23- 28 ,(2005)
O Bohnke, Conductivity measurements on nasicon and nasicon-modified materials Solid State Ionics. ,vol. 122, pp. 127- 136 ,(1999) , 10.1016/S0167-2738(99)00062-4
Litty Sebastian, J. Gopalakrishnan, Lithium ion mobility in metal oxides: a materials chemistry perspective Journal of Materials Chemistry. ,vol. 13, pp. 433- 441 ,(2003) , 10.1039/B211367H
M. Veith, M. Haas, V. Huch, Single Source Precursor Approach for the Sol−Gel Synthesis of Nanocrystalline ZnFe2O4 and Zinc−Iron Oxide Composites Chemistry of Materials. ,vol. 17, pp. 95- 101 ,(2005) , 10.1021/CM0401802
Qifeng Zhu, Fabin Qiu, Yujun Quan, Yanfeng Sun, Shaolin Liu, Zhaoyi Zou, Solid-electrolyte NASICON thick film CO2 sensor prepared on small-volume ceramic tube substrate Materials Chemistry and Physics. ,vol. 91, pp. 338- 342 ,(2005) , 10.1016/J.MATCHEMPHYS.2004.11.036
Kyle L. Fujdala, T. Don Tilley, An efficient, single-source molecular precursor to silicoaluminophosphates. Journal of the American Chemical Society. ,vol. 123, pp. 10133- 10134 ,(2001) , 10.1021/JA0167295
Yinbao Yang, Chung-Chiun Liu, Development of a NASICON-based amperometric carbon dioxide sensor Sensors and Actuators B-chemical. ,vol. 62, pp. 30- 34 ,(2000) , 10.1016/S0925-4005(99)00370-6
Atsunori Matsuda, Takao Kanzaki, Masahiro Tatsumisago, Tsutomu Minami, Comparison of structure and proton conductivity of phosphosilicate gels derived from several kinds of phosphorus-containing compounds Solid State Ionics. ,vol. 145, pp. 161- 166 ,(2001) , 10.1016/S0167-2738(01)00945-6
A. Martucci, S. Sartori, M. Guglielmi, M.L. Di Vona, S. Licoccia, E. Traversa, NMR and XRD study of the influence of the P precursor in sol-gel synthesis of NASICON powders and films Journal of The European Ceramic Society. ,vol. 22, pp. 1995- 2000 ,(2002) , 10.1016/S0955-2219(01)00536-2