Sub-solidus phase equilibria in CeO2–SrO system
作者： SV Chavan , AK Tyagi , None
DOI: 10.1016/S0040-6031(02)00076-X
关键词: Inorganic chemistry 、 Binary system 、 Solidus 、 Diffraction 、 Stoichiometry 、 Analytical chemistry 、 X-ray crystallography 、 Lattice (order) 、 Phase boundary 、 Chemistry 、 Solid solution 、 Physical and Theoretical Chemistry 、 Instrumentation (computer programming) 、 Condensed matter physics
摘要: Abstract In this communication, we report on the synthesis and characterization of a series compounds with general composition Ce 1− x Sr O 2− (0.0≤ ≤1.0), to establish detailed phase relation in CeO 2 –SrO system. The X-ray diffraction (XRD) pattern each product was refined determine solid solubility homogeneity range. limit SrO lattice, under slow cooled conditions, is represented as 0.91 0.09 1.91 (i.e. 9 mol% SrO). A careful delineation boundary revealed that stoichiometric SrCeO 3 , fact, contains little amount also. mono-phasic compound could be obtained at nominal 0.55 0.45 1.45 . 4 heat treatment used present investigation, bi-phasic mixture SrO. No new ordered phases were
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sci-hub.se 参考文章(13)
Yunfeng Gu, Gang Li, Guangyao Meng, Dingkun Peng, Sintering and electrical properties of coprecipitation prepared Ce0.8Y0.2O1.9 ceramics Materials Research Bulletin. ,vol. 35, pp. 297- 304 ,(2000) , 10.1016/S0025-5408(00)00205-1
H Inaba, Ceria-based solid electrolytes Solid State Ionics. ,vol. 83, pp. 1- 16 ,(1996) , 10.1016/0167-2738(95)00229-4
MD Mathews, BR Ambekar, AK Tyagi, None, Bulk thermal expansion studies of Th1-xCexO2 in the complete solid solution range Journal of Nuclear Materials. ,vol. 288, pp. 83- 85 ,(2001) , 10.1016/S0022-3115(00)00719-4
H. Kleykamp, The chemical state of the fission products in oxide fuels Journal of Nuclear Materials. ,vol. 131, pp. 221- 246 ,(1985) , 10.1016/0022-3115(85)90460-X
H IWAHARA, H UCHIDA, I YAMASAKI, High-temperature steam electrolysis using SrCeO3-based proton conductive solid electrolyte International Journal of Hydrogen Energy. ,vol. 12, pp. 73- 77 ,(1987) , 10.1016/0360-3199(87)90082-6
Jens Ranløv, Kurt Nielsen, Crystal structure of the high-temperature protonic conductor SrCeO3 Journal of Materials Chemistry. ,vol. 4, pp. 867- 868 ,(1994) , 10.1039/JM9940400867
Y.-W Lee, H.S Kim, S.H Kim, C.Y Joung, S.H Na, G Ledergerber, P Heimgartner, M Pouchon, M Burghartz, Preparation of simulated inert matrix fuel with different powders by dry milling method Journal of Nuclear Materials. ,vol. 274, pp. 7- 14 ,(1999) , 10.1016/S0022-3115(99)00094-X
Jens Ranløv, Bente Lebech, Kurt Nielsen, Neutron diffraction investigation of the atomic defect structure of Y-doped SrCeO3, a high-temperature protonic conductor Journal of Materials Chemistry. ,vol. 5, pp. 743- 747 ,(1995) , 10.1039/JM9950500743
K Zheng, BCH Steele, M Sahibzada, IS Metcalfe, Solid oxide fuel cells based on Ce(Gd)O2 − x electrolytes Solid State Ionics. pp. 1241- 1244 ,(1996) , 10.1016/0167-2738(96)00294-9
H.-H. Möbius, H. Witzmann, F. Zimmer, Sauerstoffionenleitende Festelektrolyte und ihre Anwendungsmöglichkeiten; Röntgenographische Untersuchungen an Fluoritphasen in den Systemen des Scandiumoxides mit Zirkon-, Cor- und Thoriumdioxid Zeitschrift für Chemie. ,vol. 4, pp. 194- 195 ,(2010) , 10.1002/ZFCH.19640040524