作者: Yun-Kai Lu , Xiu-Ping Yan
DOI: 10.1021/AC0347718
关键词: Selectivity 、 Nuclear chemistry 、 Pulmonary surfactant 、 Sorbent 、 Cadmium 、 Chemistry 、 Bromide 、 Chromatography 、 Aqueous solution 、 Molecular imprinting 、 Micelle
摘要: A hierarchical double-imprinting concept was applied to the preparation of a new organic−inorganic hybrid sorbent for selective separation Cd(II) from aqueous solution. In prepared hierarchically imprinted sorbent, both and surfactant micelles (cetyltrimethylammonium bromide) were used as templates. The through self-hydrolysis, self-condensation, co-condensation cross-linking agent (tetraethoxysilicate) functional precursor (3-(2-aminoethylamino)-propyltrimethoxysilane) in an alkaline media followed by gelation. selectivity investigated batch competitive ion-binding experiment using Zn(II) mixture. largest coefficient presence found be over 100; relative between Zn(II), 200. uptake capacity sol−gel are much higher than...