Measurement of structure H hydrate phase equilibrium and the effect of electrolytes
作者： Ulrich Hütz , Peter Englezos
DOI: 10.1016/0378-3812(95)02951-6
关键词: Clathrate hydrate 、 Salt (chemistry) 、 Hydrate 、 Methane 、 Chemistry 、 Hydrocarbon 、 Isopentane 、 Physical chemistry 、 Inorganic chemistry 、 Ternary numeral system 、 Electrolyte
摘要: Abstract Following the report from National Research Council of Canada in 1987 on a new hydrate structure, Sloan and co-workers reported first structure H phase equilibrium data 1992. The present work also reports for methane-2-methylbutane-water, methane-2,2-dimethylbutane-water, methane-tert butyl methhyl ether-water methane-adamantane-water systems. In addition, presence NaCl were obtained three systems are time. indicated that formation pressure, at given temperature, is lower than methane (structure I) pressure salt caused substantial inhibiting effect.
elsevier.com
sci-hub.se 参考文章(15)
Peter Englezos, Yee Tak Ngan, Incipient equilibrium data for propane hydrate formation in aqueous solutions of sodium chloride, potassium chloride and calcium chloride Journal of Chemical & Engineering Data. ,vol. 38, pp. 250- 253 ,(1993) , 10.1021/JE00010A017
P. Englezos, P. R. Bishnoi, Experimental study on the equilibrium ethane hydrate formation conditions in aqueous electrolyte solutions Industrial & Engineering Chemistry Research. ,vol. 30, pp. 1655- 1659 ,(1991) , 10.1021/IE00055A038
C. A. Frost, Polydrusus Sericeus Schall Psyche. ,vol. 53, pp. 51- 51 ,(1946) , 10.1155/1946/83061
J. A. Ripmeester, C. I. Ratcliffe, Xenon-129 NMR studies of clathrate hydrates: new guests for structure II and structure H The Journal of Physical Chemistry. ,vol. 94, pp. 8773- 8776 ,(1990) , 10.1021/J100388A006
Ajay P. Mehta, E. Dendy Sloan, Structure H hydrate phase equilibria of methane + liquid hydrocarbon mixtures Journal of Chemical & Engineering Data. ,vol. 38, pp. 580- 582 ,(1993) , 10.1021/JE00012A027
John A. Ripmeester, John S. Tse, Christopher I. Ratcliffe, Brian M. Powell, A new clathrate hydrate structure Nature. ,vol. 325, pp. 135- 136 ,(1987) , 10.1038/325135A0
Peter Englezos, Yee Tak Ngan, Effect of polyethylene oxide on gas hydrate phase equilibria Fluid Phase Equilibria. ,vol. 92, pp. 271- 288 ,(1994) , 10.1016/0378-3812(94)80051-0
Ajay P. Mehta, E. Dendy Sloan, Structure H Hydrate Phase Equilibria of Paraffins, Naphthenes, and Olefins with Methane Journal of Chemical & Engineering Data. ,vol. 39, pp. 887- 890 ,(1994) , 10.1021/JE00016A056
John S. Tse, Thermal expansion of structure-H clathrate hydrates Journal of Inclusion Phenomena and Macrocyclic Chemistry. ,vol. 8, pp. 25- 32 ,(1990) , 10.1007/BF01131285
J.P. Lederhos, R.L. Christiansen, E.D. Sloan, A first order method of hydrate equilibrium estimation and its use with new structures Fluid Phase Equilibria. ,vol. 83, pp. 445- 454 ,(1993) , 10.1016/0378-3812(93)87049-7