Ethyl oleate ozonide as an epoxidation tool of C60 and C70 fullerenes
作者： Ornella Ursini , Franco Cataldo
DOI: 10.1080/1536383X.2016.1271790
关键词: Homolysis 、 Ozonide 、 Peroxide 、 Decomposition 、 Organic chemistry 、 Reaction rate constant 、 Chemistry 、 Fullerene 、 Ethyl oleate 、 Kinetics
摘要: ABSTRACTWhen dissolved in ethyl oleate secondary ozonide, both C60 and C70 fullerenes undergo a series of epoxidation reactions. The pseudofirst-order kinetic rate constants this process were determined spectrophotometrically at various temperatures the activation energy for through ozonide was found 25.9 kcal/mol. Furthermore, more reactive than with ozonide. kinetics compared photo-oxidation auto-oxidation pure oleate. starts from homolysis peroxide group 1,2,4-trioxolane ring Thus, it is suggested that have potential as decomposition agents ozonides some technological applications.
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