1.19 Carbonyl and Imine Activation

作者: H. Miyabe , Y. Takemoto

DOI: 10.1016/B978-0-08-097742-3.00125-7

关键词: Brønsted–Lowry acid–base theoryNucleophileCatalysisPolymer chemistryX ray analysisIonic bondingOrganic chemistryImineElectrophileChemistryIon

摘要: This chapter highlights the catalytic activation of C O and N bonds in nucleophilic additions to these π-bonds by noncovalent organocatalysts, such as hydrogen-bonding catalysts (diols, ureas, guanidines) Bronsted acids (phosphoric carboacids) well ionic electrophile via counter anion recognition peptide-derived thioureas.

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