作者: Paola Manca , Roberta Scanu , Antonio Zucca , Gavino Sanna , Nadia Spano
DOI: 10.1016/J.POLYMER.2013.05.026
关键词: Conductive polymer 、 Homoleptic 、 Polymerization 、 Ruthenium 、 Terpyridine 、 Electrochemistry 、 Moiety 、 Terthiophene 、 Materials science 、 Photochemistry
摘要: Abstract Synthesis and electrochemical spectroscopic characterization of a 2:1 homoleptic Ru(II) complex, [Ru(TAT)2]2+ (TAT = 4′-(2,2′:5′,2″-terthien-3′-ethynyl)-2,2′:6′,2″-terpyridine), are here reported. The complex has been used as starting material to originate the relevant metallopolymer poly[Ru(TAT)2], deriving from anodic electropolymerization on terthiophene moiety. characterized by techniques, comparing it corresponding conducting polymer poly(TAT). Furthermore, revealed unexpected behaviour cathodically polymerize. Such electrochemically optically characterized, its was compared originated polymerization.