Effect of the absorption of hydrogen by nickel on its anodic dissolution and corrosion in acidic solutions

作者: Ya.B. Skuratnik , A.E. Kozachinskii , A.P. Pchelnikov , V.V. Losev

DOI: 10.1016/0022-0728(93)03108-2

关键词: Anaerobic corrosionNickelElectrochemistryInorganic chemistryDissolutionPolarization (electrochemistry)CorrosionChemistryHydrogenMetal

摘要: Abstract A computer-aided method comprising various electrochemical measurements and continuous measurement of the dissolution rates metal using a radiotracer technique with synchronous processing data obtained was used to study effect hydrogen absorbed by nickel during preliminary cathodic polarization corrosion on subsequent anodic behaviour in 0.5 M H2SO4 solution. It found that initial period potentiostatic polarization, preferential ionization is limited non-steady state diffusion surface, while strongly inhibited. The beneficial influence this inhibiting discussed.

参考文章(9)
R. McKibben, R.M. Sharp, D.A. Harrington, B.G. Pound, G.A. Wright, A potentiostatic double-step method for measuring hydrogen atom diffusion and trapping in metal electrodes—I. Theory Acta Metallurgica. ,vol. 35, pp. 253- 262 ,(1987) , 10.1016/0001-6160(87)90233-1
A.P. Pchelnikov, A.D. Sitnikov, I.K. Marshakov, V.V. Losev, A study of the kinetics and mechanism of brass dezincification by radiotracer and electrochemical methods Electrochimica Acta. ,vol. 26, pp. 591- 600 ,(1981) , 10.1016/0013-4686(81)80025-4
Sidney M. Selis, Laurence P. McGinnis, Elmer S. McKee, James T. Smith, Electrode Reactions and Iron Oxide Selection for the Thermal Cell Mg∕LiCl-KCl∕FeO[sub x], Ni Journal of The Electrochemical Society. ,vol. 110, pp. 469- 476 ,(1963) , 10.1149/1.2425796
Rajan N. Iyer, Howard W. Pickering, Mehrooz Zamanzadeh, Analysis of Hydrogen Evolution and Entry into Metals for the Discharge‐Recombination Process Journal of The Electrochemical Society. ,vol. 136, pp. 2463- 2470 ,(1989) , 10.1149/1.2097429
Z. Szklarska-Smialowska, M. Smialowski, Electrochemical Study of the Nickel-Hydrogen System Journal of The Electrochemical Society. ,vol. 110, pp. 444- 448 ,(1963) , 10.1149/1.2425783