Effects of steam activation on the pore structure and surface chemistry of activated carbon derived from bamboo waste
作者： Yan-Juan Zhang , Zhen-Jiao Xing , Zheng-Kang Duan , Meng Li , Yin Wang
DOI: 10.1016/J.APSUSC.2014.07.126
关键词: Organic chemistry 、 Activated carbon 、 Pyrolysis 、 Adsorption 、 Char 、 Fourier transform infrared spectroscopy 、 Chemical engineering 、 X-ray photoelectron spectroscopy 、 Titration 、 Chemistry 、 BET theory
摘要: Abstract The effects of steam activation on the pore structure evolution and surface chemistry activated carbon (AC) obtained from bamboo waste were investigated. Nitrogen adsorption–desorption isotherms revealed that higher temperatures and/or times promoted creation new micropores widened existing micropores, consequently decreasing area total volume. Optimum conditions included an temperature 850 °C, time 120 min, flush generated deionized water 0.2 cm 3 min −1 . Under these conditions, AC with a BET 1210 m 2 g volume 0.542 cm −3 was obtained. Changes in determined through Boehm titration, pH measurement, Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron (XPS). Results presence large number basic groups pyrolyzed char AC. Steam did not affect species oxygen-containing but changed contents when compared char. Scanning electron microscopy used to observe morphology products. under optimum showed monolayer adsorption capacity 330 mg g for methylene blue (MB), which demonstrates its excellent potential MB applications.
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sci-hub.se 参考文章(41)
Fred. Ellerbusch, Paul N. Cheremisinoff, Carbon adsorption handbook ,(1978)
Norhusna Mohamad Nor, Lee Chung Lau, Keat Teong Lee, Abdul Rahman Mohamed, Synthesis of activated carbon from lignocellulosic biomass and its applications in air pollution control—a review Journal of environmental chemical engineering. ,vol. 1, pp. 658- 666 ,(2013) , 10.1016/J.JECE.2013.09.017
Philippe Burg, Peggy Fydrych, Denise Cagniant, Gérard Nanse, Jan Bimer, Anna Jankowska, The characterization of nitrogen-enriched activated carbons by IR, XPS and LSER methods Carbon. ,vol. 40, pp. 1521- 1531 ,(2002) , 10.1016/S0008-6223(02)00004-0
N.V. Sych, S.I. Trofymenko, O.I. Poddubnaya, M.M. Tsyba, V.I. Sapsay, D.O. Klymchuk, A.M. Puziy, Porous structure and surface chemistry of phosphoric acid activated carbon from corncob Applied Surface Science. ,vol. 261, pp. 75- 82 ,(2012) , 10.1016/J.APSUSC.2012.07.084
Jing-Hong Zhou, Zhi-Jun Sui, Jun Zhu, Ping Li, De Chen, Ying-Chun Dai, Wei-Kang Yuan, Characterization of surface oxygen complexes on carbon nanofibers by TPD, XPS and FT-IR Carbon. ,vol. 45, pp. 785- 796 ,(2007) , 10.1016/J.CARBON.2006.11.019
K. S. W. Sing, Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) Pure and Applied Chemistry. ,vol. 57, pp. 603- 619 ,(1985) , 10.1351/PAC198557040603
Guillermo San Miguel,, Geoffrey D. Fowler, Christopher J. Sollars, A study of the characteristics of activated carbons produced by steam and carbon dioxide activation of waste tyre rubber Carbon. ,vol. 41, pp. 1009- 1016 ,(2003) , 10.1016/S0008-6223(02)00449-9
Edward L.K. Mui, W.H. Cheung, Marjorie Valix, Gordon McKay, Activated carbons from bamboo scaffolding using acid activation Separation and Purification Technology. ,vol. 74, pp. 213- 218 ,(2010) , 10.1016/J.SEPPUR.2010.06.007
A.W.M. Ip, J.P. Barford, G. McKay, Production and comparison of high surface area bamboo derived active carbons. Bioresource Technology. ,vol. 99, pp. 8909- 8916 ,(2008) , 10.1016/J.BIORTECH.2008.04.076
Hakan Demiral, İlknur Demiral, Belgin Karabacakoğlu, Fatma Tümsek, Production of activated carbon from olive bagasse by physical activation Chemical Engineering Research and Design. ,vol. 89, pp. 206- 213 ,(2011) , 10.1016/J.CHERD.2010.05.005