Main group metal - organic frameworks of Bi(V) and Pb(II) derived from 2-(4,6-diamino-3-(3-amino-6- (1-methyamino-ethyl) tetrahydropyran-2-yl) oxy-2-hydroxy-cyclohexoxy)-5-methyl-4-methylamino- tetrahydropyran-3,5-diol and their molecular modeling
作者： Rajiv Kumar , Parashuram Mishra
DOI: 10.1080/10241220701687941
关键词: Molecular model 、 Chemistry 、 Metal-organic framework 、 Cell dimension 、 Tetrahydropyran 、 Main group element 、 Proton NMR 、 Diol 、 Crystallography
摘要: Main group metal complexes of Bi(V) and Pb(II) were synthesized with an organic framework (OF) 2-[4,6-diamino-3-[3-amino-6-(1-methyamino-ethyl) tetrahydropyran-2-yl] oxy-2-hydroxy-cyclohexoxy]-5-methyl-4-methylamino-tetrahydropyran-3,5-diol (L). Conformational changes the binding abilities toward identified by various physiochemical spectroscopic measurements including IR, 1H NMR, UV – vis, molecular modeling, X-ray powder diffractometry. The lattice parameters frameworks (MOFs) calculated as follows: cell dimension for [Bi(V)L] complex, a = 9.8355 (A), b = 9.8355 c = 21.78695 α = 90.00°, β = 90.00°, γ = 90.00°; a = 11.59609 b = 15.0373 c = 6.6854 β = 99.000°, γ = 90.00° at 1.54056A°. Particle size (nm) was found to be 10.75 8.817 nm, respectively. Molecular models represent a better understanding arrangement of...
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