Copper-catalyzed oxidative C(sp3)–H/N–H coupling of sulfoximines and amides with simple alkanes via a radical process

作者: Fan Teng , Song Sun , Yan Jiang , Jin-Tao Yu , Jiang Cheng

DOI: 10.1039/C5CC00839E

关键词: Bond formationStereochemistryMedicinal chemistryOxidative phosphorylationCopper catalyzedCoupling (electronics)AnilineArylChemistry

摘要: … This protocol involved C(sp 3 )–N bond formation via a radical pathway and tolerated a series of functional groups, such as chloro, methyl and aryl, on the phenyl rings. Apart from …

参考文章(56)
Nattawut Yongpruksa, Nathan L. Calkins, Michael Harmata, Efficient palladium-catalyzed N-arylation of a sulfoximine with aryl chlorides Chemical Communications. ,vol. 47, pp. 7665- 7667 ,(2011) , 10.1039/C1CC12444G
John T. Groves, Thomas E. Nemo, Aliphatic hydroxylation catalyzed by iron porphyrin complexes Journal of the American Chemical Society. ,vol. 105, pp. 6243- 6248 ,(1983) , 10.1021/JA00358A009
Wei Liu, John T. Groves, Manganese Porphyrins Catalyze Selective C-H Bond Halogenations Journal of the American Chemical Society. ,vol. 132, pp. 12847- 12849 ,(2010) , 10.1021/JA105548X
Carsten Bolm, Seong Jun Park, Hannah Baars, Stefanie Mersmann, Helmut Buschmann, Jens Malte Baron, Philipp M. Amann, Katharina Czaja, Henner Hollert, Kerstin Bluhm, Regine Redelstein, N-cyano sulfoximines: COX inhibition, anticancer activity, cellular toxicity, and mutagenicity. ChemMedChem. ,vol. 8, pp. 217- 220 ,(2013) , 10.1002/CMDC.201200403
Yefeng Zhu, Yunyang Wei, Copper catalyzed direct alkenylation of simple alkanes with styrenes Chemical Science. ,vol. 5, pp. 2379- 2382 ,(2014) , 10.1039/C4SC00093E
Arkaitz Correa, Carsten Bolm, Iron-Catalyzed CN Cross-Coupling of Sulfoximines with Aryl Iodides Advanced Synthesis & Catalysis. ,vol. 350, pp. 391- 394 ,(2008) , 10.1002/ADSC.200700508
Anand Pariyar, Suranjana Bose, Achintesh Narayan Biswas, Purak Das, Pinaki Bandyopadhyay, Catalytic hydrocarbon oxidation by iron complex of 5,10,15-tris(difluorophenyl)corrole via activation of hydroperoxides Catalysis Communications. ,vol. 32, pp. 23- 27 ,(2013) , 10.1016/J.CATCOM.2012.11.026
Bingnan Du, Bo Jin, Peipei Sun, Syntheses of sulfides and selenides through direct oxidative functionalization of C(sp3)-H bond. Organic Letters. ,vol. 16, pp. 3032- 3035 ,(2014) , 10.1021/OL5011449
Honglin Zhang, Changduo Pan, Ning Jin, Zhangxi Gu, Hongwen Hu, Chengjian Zhu, Metal-free cascade construction of C–C bonds by activation of inert C(sp3)–H bonds Chemical Communications. ,vol. 51, pp. 1320- 1322 ,(2015) , 10.1039/C4CC08629E