Preparation and properties of waterborne interpenetrating polymer networks composed of polyurethaneurea and graft vinyl ester resin
作者： Teng Su , Chun Pu Hu
DOI: 10.1002/APP.30615
关键词: Polymer chemistry 、 Polymer 、 Polyol 、 Chemical modification 、 Interpenetrating polymer network 、 Materials science 、 Polyester 、 Side chain 、 Isophorone diisocyanate 、 Vinyl ester
摘要: Various waterborne interpenetrating polymer networks (IPNs) composed of polyurethaneurea (PUU) and graft vinyl ester resin were prepared from polyester polyol, dimethylolpropionic acid, isophorone diisocyanate, ethylenediamine a well-defined containing butanol side chains (BO-g-VER). These anionic IPN aqueous dispersions stable at the ambient temperature for >1 yr, also had excellent stability low high temperatures. The experimental results showed that introduction BO-g-VER network has not only greatly affected particle morphology, rheological behavior these dispersions, but rendered films with augmented surface hydrophobicity as well water-resistance performance mechanical properties. A synergistic effect was observed certain composition (20 wt %) to give significant reinforcement PUU, resulting compatibility and/or interpenetration between PUU network. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci,
sci-hub.se 参考文章(26)
Lian Hua Fan, Chun Pu Hu, Zhao Qi Pan, Zhi Ping Zhang, Sheng Kang Ying, Polymerization of polyurethane and vinyl ester resin interpenetrating polymer networks during reaction injection moulding process Polymer. ,vol. 38, pp. 3609- 3616 ,(1997) , 10.1016/S0032-3861(96)00919-6
Hong Li, Zhao Bin Zhang, Chun Pu Hu, Shu Sen Wu, Sheng Kang Ying, Surface composition and property of film prepared with aqueous dispersion of polyurethaneurea-acrylate including fluorinated block copolymer European Polymer Journal. ,vol. 40, pp. 2195- 2201 ,(2004) , 10.1016/J.EURPOLYMJ.2004.02.010
W.-M. Kulicke, O. Arendt, M. Berger, Characterization of hydroxypropylmethyl- cellulose-stabilized emulsions Colloid and Polymer Science. ,vol. 276, pp. 1024- 1031 ,(1998) , 10.1007/S003960050342
Sheng Kang Ying, Lian Hua Fan, Chun Pu Hu, Thermal analysis during the formation of polyurethane and vinyl ester resin interpenetrating polymer networks Polymer. ,vol. 37, pp. 975- 981 ,(1996) , 10.1016/0032-3861(96)87280-6
Gui You Wang, Yu Ling Wang, Chun Pu Hu, Interpenetrating polymer networks of polyurethane and graft vinyl ester resin : polyurethane formed with toluene diisocyanate European Polymer Journal. ,vol. 36, pp. 735- 742 ,(2000) , 10.1016/S0014-3057(99)00113-5
Lin Jiang, Yong Lin Chen, Chun Pu Hu, Polyurethaneurea aqueous dispersions prepared with diethyltoluenediamine as chain extender Journal of Coatings Technology and Research. ,vol. 4, pp. 59- 66 ,(2007) , 10.1007/S11998-007-9010-7
Byung Kim, Jung Shin, Modification of waterborne polyurethane by forming latex interpenetrating polymer networks with acrylate rubber Colloid and Polymer Science. ,vol. 280, pp. 716- 724 ,(2002) , 10.1007/S00396-002-0672-5
Ajaya K. Nanda, Douglas A. Wicks, Samy A. Madbouly, Joshua U. Otaigbe, Nanostructured Polyurethane/POSS Hybrid Aqueous Dispersions Prepared by Homogeneous Solution Polymerization Macromolecules. ,vol. 39, pp. 7037- 7043 ,(2006) , 10.1021/MA060809H
O. R. Pardini, J. I. Amalvy, FTIR, 1H‐NMR spectra, and thermal characterization of water‐based polyurethane/acrylic hybrids Journal of Applied Polymer Science. ,vol. 107, pp. 1207- 1214 ,(2008) , 10.1002/APP.27188
Ten-Chin Wen, Ming-Sieng Wu, Chien-Hsin Yang, Spectroscopic Investigations of Poly(oxypropylene)glycol-Based Waterborne Polyurethane Doped with Lithium Perchlorate Macromolecules. ,vol. 32, pp. 2712- 2720 ,(1999) , 10.1021/MA9804489