POSS-based microporous polymers: Efficient Friedel-Crafts synthesis, CO2 capture and separation properties
作者： Jun Liu , Yunfei Liu , Xiaowei Jiang , Yali Luo , Yinong Lyu
DOI: 10.1016/J.MICROMESO.2017.05.043
关键词: Selective adsorption 、 Microporous material 、 Polymer 、 Cyanuric chloride 、 Adsorption 、 Chemical engineering 、 Organic chemistry 、 Friedel–Crafts reaction 、 Selectivity 、 Materials science 、 Thermal stability
摘要: Abstract Two kinds of POSS-based microporous organic polymers (PMOPs) were prepared by cost-effective Friedel-Crafts reaction octaphenylsilsesquioxanes with p-dimethoxybenzene (PMOP-1) or cyanuric chloride (PMOP-2). PMOP-1 high surface area 806 m2 g−1 exhibited reasonable CO2 adsorption (2.59 mmol g−1, 273 K/1 bar) and selectivity, whereas PMOP-2 lower (559 m2 g−1) showed a higher CO2/N2 selectivity (30.0) CO2/CH4 (6.8) at 273 K/1 bar due to the amount nitrogen incorporated within structure. The correlation between performance PMOPs in capture/separation their properties such as area, active sites, heat was investigated. combination method, thermal stability, selective make these materials potential candidates for application capture separation technology.
sci-hub.se 参考文章(49)
Liangxiao Tan, Buyi Li, Xinjia Yang, Weixing Wang, Bien Tan, Knitting hypercrosslinked conjugated microporous polymers with external crosslinker Polymer. ,vol. 70, pp. 336- 342 ,(2015) , 10.1016/J.POLYMER.2015.06.026
John J. Morrison, Christopher J. Love, Bruce W. Manson, Ian J. Shannon, Russell E. Morris, Synthesis of functionalised porous network silsesquioxane polymers Journal of Materials Chemistry. ,vol. 12, pp. 3208- 3212 ,(2002) , 10.1039/B204240A
V.V. Podlesnyuk, J. Hradil, E. Králová, Sorption of organic vapours by macroporous and hypercrosslinked polymeric adsorbents Reactive and Functional Polymers. ,vol. 42, pp. 181- 191 ,(1999) , 10.1016/S1381-5148(98)00067-4
Yali Luo, Buyi Li, Wei Wang, Kangbing Wu, Bien Tan, Hypercrosslinked Aromatic Heterocyclic Microporous Polymers: A New Class of Highly Selective CO2 Capturing Materials Advanced Materials. ,vol. 24, pp. 5703- 5707 ,(2012) , 10.1002/ADMA.201202447
Huanyu Zhao, Zhao Jin, Hongmin Su, Jinlei Zhang, Xiangdong Yao, Huijun Zhao, Guangshan Zhu, Target synthesis of a novel porous aromatic framework and its highly selective separation of CO2/CH4 Chemical Communications. ,vol. 49, pp. 2780- 2782 ,(2013) , 10.1039/C3CC38474H
Xiaofei Jing, Fuxing Sun, Hao Ren, Yuyang Tian, Mingyi Guo, Lina Li, Guangshan Zhu, Targeted synthesis of micro–mesoporous hybrid material derived from octaphenylsilsesquioxane building units Microporous and Mesoporous Materials. ,vol. 165, pp. 92- 98 ,(2013) , 10.1016/J.MICROMESO.2012.07.048
David B. Cordes, Paul D. Lickiss, Franck Rataboul, Recent Developments in the Chemistry of Cubic Polyhedral Oligosilsesquioxanes Chemical Reviews. ,vol. 110, pp. 2081- 2173 ,(2010) , 10.1021/CR900201R
Andrew I. Cooper, Conjugated Microporous Polymers Advanced Materials. ,vol. 21, pp. 1291- 1295 ,(2009) , 10.1002/ADMA.200801971
Dengxu Wang, Lei Xue, Liguo Li, Bei Deng, Shengyu Feng, Hongzhi Liu, Xian Zhao, None, Rational Design and Synthesis of Hybrid Porous Polymers Derived from Polyhedral Oligomeric Silsesquioxanes via Heck Coupling Reactions Macromolecular Rapid Communications. ,vol. 34, pp. 861- 866 ,(2013) , 10.1002/MARC.201200835
Ye Peng, Teng Ben, Jun Xu, Ming Xue, Xiaofei Jing, Feng Deng, Shilun Qiu, Guangshan Zhu, A covalently-linked microporous organic-inorganic hybrid framework containing polyhedral oligomeric silsesquioxane moieties Dalton Transactions. ,vol. 40, pp. 2720- 2724 ,(2011) , 10.1039/C0DT01268H