Structure of crystalline and amorphous Ge probed by X-ray absorption and diffraction techniques

作者: A. Di Cicco , E. Principi , M. Minicucci , S. De Panfilis , A. Filipponi

DOI: 10.1080/08957950410001661864

关键词: Amorphous solidX-ray absorption spectroscopyMaterials scienceAnalytical chemistryDiffractionExtended X-ray absorption fine structureX-ray crystallographyAbsorption spectroscopyCrystallizationDiamond anvil cell

摘要: Results of experiments dedicated to the study structure under high pressure amorphous Ge (a-Ge) and crystalline (c-Ge) are reported. Energy-dispersive X-ray diffraction measurements c-Ge have been collected at DW11A beamline (DCI, LURE) using a heatable diamond anvil cell as device up 500 K. The a-Ge performed ESRF, advanced set-up available BM29 beamline, which allows simultaneous collection absorption spectroscopy data patterns used monitor crystallization sample in Paris–Edinburgh large-volume cell. new structural allowed us obtain reliable determination lattice parameters function temperature first-neighbor distance distribution a-Ge.

参考文章(24)
Keiji Tanaka, Amorphous Ge under pressure Physical Review B. ,vol. 43, pp. 4302- 4307 ,(1991) , 10.1103/PHYSREVB.43.4302
G. J. Piermarini, S. Block, J. D. Barnett, R. A. Forman, Calibration of the pressure dependence of the R1 ruby fluorescence line to 195 kbar Journal of Applied Physics. ,vol. 46, pp. 2774- 2780 ,(1975) , 10.1063/1.321957
O. Shimomura, S. Minomura, N. Sakai, K. Asaumi, K. Tamura, J. Fukushima, H. Endo, Pressure-induced semiconductor-metal transitions in amorphous Si and Ge Philosophical Magazine. ,vol. 29, pp. 547- 558 ,(1974) , 10.1080/14786437408213238
J.M. Besson, R.J. Nelmes, G. Hamel, J.S. Loveday, G. Weill, S. Hull, Neutron powder diffraction above 10 GPa Physica B: Condensed Matter. ,vol. 180-181, pp. 907- 910 ,(1992) , 10.1016/0921-4526(92)90505-M
Adriano Filipponi, Michael Borowski, Daniel T Bowron, Stuart Ansell, Andrea Di Cicco, Simone De Panfilis, Jean-Paul Itie, None, An experimental station for advanced research on condensed matter under extreme conditions at the European Synchrotron Radiation Facility - BM29 beamline Review of Scientific Instruments. ,vol. 71, pp. 2422- 2432 ,(2000) , 10.1063/1.1150631
E.G. Ponyatovsky, O.I. Barkalov, Pressure—induced amorphous phases Materials Science Reports. ,vol. 8, pp. 147- 191 ,(1992) , 10.1016/0920-2307(92)90007-N
M. I. McMahon, R. J. Nelmes, New Structural Systematics in the II–VI, III–V, and Group-IV Semiconductors at High Pressure Physica Status Solidi B-basic Solid State Physics. ,vol. 198, pp. 389- 402 ,(1996) , 10.1002/PSSB.2221980151
J Crain, G J Ackland, S J Clark, Exotic structures of tetrahedral semiconductors Reports on Progress in Physics. ,vol. 58, pp. 705- 754 ,(1995) , 10.1088/0034-4885/58/7/001
J. M. Leger, C. Chateau, A. Lacam, SrB4O7 : Sm2+ pressure optical sensor : investigations in the megabar range Journal of Applied Physics. ,vol. 68, pp. 2351- 2354 ,(1990) , 10.1063/1.346543