The initial characteristics of the polypyrrole based aqueous rechargeable batteries with supercapattery characteristics
作者： Branimir N. Grgur , Marija Janačković , Branimir Z. Jugović , Milica M. Gvozdenović
DOI: 10.1016/J.MSEB.2019.04.013
关键词: Materials science 、 Electrolyte 、 Zinc 、 Lead oxide 、 Aqueous solution 、 Electrochemistry 、 Polypyrrole 、 Chemical engineering 、 Chloride 、 Battery (electricity)
摘要: Abstract The electrochemically synthesized polypyrrole (PPy) is investigated as a possible active material of the low-cost aqueous based secondary power sources in combination with zinc, lead oxide, and sulfate. discharge capacity chloride-based electrolyte (for Zn|PPy cell) range 110 mAh g−1 PPy, while sulfate-based ∼150 mAh g−1 PPy PbSO4|PPy PPy|PbO2 cells), which close to theoretically calculated values. Electrochemical electrical parameters, reactions cells, specific capacity, capacitance, energy, power, for Zn|PPy, cells are determined. In addition, energy efficiency, considered systems estimated. Obtained values could classified battery type hybrid superacapacitors or “supercapattery”.
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