Biosorption of chromium (III) by orange (Citrus cinensis) waste: Batch and continuous studies

作者: A.B. Pérez Marín , M.I. Aguilar , V.F. Meseguer , J.F. Ortuño , J. Sáez

DOI: 10.1016/J.CEJ.2009.07.034

关键词: WastewaterParticle sizeSorptionBiosorptionChromatographyAdsorptionChromiumNuclear chemistryAqueous solutionChemistryOrange (colour)

摘要: Abstract The present study explores the ability of orange waste biomass to remove Cr (III) from aqueous solutions. Batch kinetic and isotherm studies were carried out on a laboratory scale evaluate adsorption capacity waste. effects particle size, adsorbent dose solution pH removal also studied. results showed that higher dosage pH, percentage metal removal. No significant influence size sorption was observed in experimental conditions A revealed onto gradual process equilibrium reached within 3 days. pseudo-second order model most appropriate describe data. Equilibrium assays displayed maximum ranging 0.57 mmol/g 1.44 mmol/g when increased 5, according Sips model, which along with Redlich–Peterson equation, is very suitable for correlating use studied chromium continuous mode successful breakthrough curves adequately represented by BDST model. Due slow kinetics waste, batch than assays.

参考文章(45)
D. C. Ayres, B. J. Alloway, Chemical principles of environmental pollution ,(1993)
Harshala Parab, Shreeram Joshi, Niyoti Shenoy, Arvind Lali, U.S. Sarma, M. Sudersanan, Determination of kinetic and equilibrium parameters of the batch adsorption of Co(II), Cr(III) and Ni(II) onto coir pith Process Biochemistry. ,vol. 41, pp. 609- 615 ,(2006) , 10.1016/J.PROCBIO.2005.08.006
B. Volesky, Z. R. Holan, Biosorption of Heavy Metals ,(1990)
G ANNADURAI, R JUANG, D LEE, Use of cellulose-based wastes for adsorption of dyes from aqueous solutions. Journal of Hazardous Materials. ,vol. 92, pp. 263- 274 ,(2002) , 10.1016/S0304-3894(02)00017-1
Umesh K. Garg, M.P. Kaur, V.K. Garg, Dhiraj Sud, Removal of hexavalent chromium from aqueous solution by agricultural waste biomass. Journal of Hazardous Materials. ,vol. 140, pp. 60- 68 ,(2007) , 10.1016/J.JHAZMAT.2006.06.056
G. Blázquez, F. Hernáinz, M. Calero, M.A. Martín-Lara, G. Tenorio, The effect of pH on the biosorption of Cr (III) and Cr (VI) with olive stone. Chemical Engineering Journal. ,vol. 148, pp. 473- 479 ,(2009) , 10.1016/J.CEJ.2008.09.026
Julio C.P. Vaghetti, Eder C. Lima, Betina Royer, Bruna M. da Cunha, Natali F. Cardoso, Jorge L. Brasil, Silvio L.P. Dias, Pecan nutshell as biosorbent to remove Cu(II), Mn(II) and Pb(II) from aqueous solutions Journal of Hazardous Materials. ,vol. 162, pp. 270- 280 ,(2009) , 10.1016/J.JHAZMAT.2008.05.039
Potsangbam Albino Kumar, Saswati Chakraborty, Fixed-bed column study for hexavalent chromium removal and recovery by short-chain polyaniline synthesized on jute fiber Journal of Hazardous Materials. ,vol. 162, pp. 1086- 1098 ,(2009) , 10.1016/J.JHAZMAT.2008.05.147
Julio C.P. Vaghetti, Eder C. Lima, Betina Royer, Jorge L. Brasil, Bruna M. da Cunha, Nathalia M. Simon, Natali F. Cardoso, Caciano P. Zapata Noreña, APPLICATION OF BRAZILIAN-PINE FRUIT COAT AS A BIOSORBENT TO REMOVAL OF CR(VI) FROM AQUEOUS SOLUTION. KINETICS AND EQUILIBRIUM STUDY Biochemical Engineering Journal. ,vol. 42, pp. 67- 76 ,(2008) , 10.1016/J.BEJ.2008.05.021