Synthesis of “living” polyolefins with soluble Ziegler-Natta catalysts and application to block copolymerization

作者: Yoshiharu Doi , Tominaga Keii

DOI: 10.1007/3-540-15786-7_10

关键词: CatalysisPolymerizationOrganic chemistryCopolymerMolar mass distributionChain propagationCoordination polymerizationChemistryNattaEthylene

摘要: “Living” polymerization is of great utility both in understanding the mechanism chain propagation reactions and synthesizing well-defined block copolymers. In this review we deal with development soluble Ziegler-Natta catalysts for living coordination ethylene α-olefins discuss possibility synthesis new

参考文章(100)
Gisela Henrici Olivé, Salvador Olivé, Hideto Sotobayashi, Jürgen Springer, Giuseppe Allegra, IW Bassi, Koordinative Polymerisation an löslichen Übergangsmetall-Katalysatoren Springer Berlin Heidelberg. pp. 421- 472 ,(1969) , 10.1007/BFB0051141
Umberto Zucchini, Giuliano Cecchin, Control of molecular-weight distribution in polyolefins synthesized with Ziegler-Natta catalytic systems Springer, Berlin, Heidelberg. pp. 101- 153 ,(1983) , 10.1007/BFB0017586
G. Henrici-Olivé, S. Olivé, Oligomerization of ethylene with soluble transition-metal catalysts Advances in Polymer Science. pp. 1- 30 ,(1974) , 10.1007/3-540-06910-0_1
A. D. Ketley, The stereochemistry of macromolecules M. Dekker. ,(1967)
S. Olivé, G. Henrici-Olivé, Coordination and catalysis ,(1976)
C. F. H. Tipper, C. H. Bamford, Comprehensive Chemical Kinetics ,(1976)
Hansjörg Sinn, Walter Kaminsky, Ziegler-Natta Catalysis ChemInform. ,vol. 18, pp. 99- 149 ,(1980) , 10.1016/S0065-3055(08)60307-X