Ketone Synthesis by Intramolecular Acylation of Organorhodium(I) with Ester
作者： Tomoya Miura , Taisuke Sasaki , Hiroki Nakazawa , Masahiro Murakami
DOI: 10.1021/JA043123I
关键词: Chemistry 、 Catalyst selectivity 、 Bond formation 、 Catalysis 、 Acylation 、 Catalytic cycle 、 Ketone synthesis 、 Stereochemistry 、 Intramolecular force 、 Colloid and Surface Chemistry 、 Biochemistry 、 General chemistry
摘要: New cyclization reactions forming cyclic ketones were developed wherein an intermediate organorhodium(I) species underwent intramolecular acylation with ester group. A 2-norbornanone skeleton is constructed in a single operation through successive multiple carbon−carbon bond formation. The ended up generation of alkoxyrhodium(I) to promote the next catalytic cycle.
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