Catalytic Conversion of Glucose to 5-Hydroxymethyfurfural Over B 2 O 3 Supported Solid Acids Catalysts
作者： Bin Han , Peng Zhao , Rong He , Tinghua Wu , Ying Wu
DOI: 10.1007/S12649-017-9971-4
关键词: Pyridine 、 Adsorption 、 X-ray photoelectron spectroscopy 、 Chemistry 、 Inorganic chemistry 、 Lewis acids and bases 、 Total acid 、 Yield (chemistry) 、 Brønsted–Lowry acid–base theory 、 Catalysis
摘要: A series of supported B2O3/ZrO2–Al2O3 (BZA) catalysts with different loading B2O3 were prepared and characterized by XRD, FT-IR, XPS, NH3-TPD, N2 adsorption–desorption FT-IR (pyridine adsorption). These applied for direct conversion glucose to 5-hydroxymethylfurfural (HMF). An optimized HMF yield 41.2% at a 90.8% was obtained within 4 h 150 °C over (20 wt%)/ZrO2–Al2O3 (BZA-0.20). The best catalytic performance BZA-0.20 associated the highest amount total acid. simultaneously bearing Lewis acid Bronsted sites more efficient production from glucose.
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