Electrical properties and mesostructure of carbon black-filled polymers

作者: François Carmona , Jérôme Ravier

DOI: 10.1016/S0008-6223(01)00166-X

关键词: Novel techniquePolymerCarbon blackConductivityCarbonPercolationElectrical connectionNanotechnologyPercolation theoryMaterials scienceStatistical physics

摘要: Abstract The electrical properties of carbon black-filled polymers are briefly reviewed. published experimental findings compared to the predictions current models related percolation theory. It is deduced that, although this theory applies qualitatively most observed behaviors, it fails give account quantitatively many others, like for example location well-known conductivity transition. One concludes that basically one may suspect model mesotructure involved in approach not fully appropriate. New results obtained by means a novel technique allowing powerful investigation connection among conducting particles throughout heterogeneous material reported. A preliminary conclusion mesostructure can be qualitative agreement with model.

参考文章(14)
J. Ravier, F. Houzé, F. Carmona, O. Schneegans, H. Saadaoui, Mesostructure of polymer/carbon black composites observed by conductive probe atomic force microscopy Carbon. ,vol. 39, pp. 314- 318 ,(2001) , 10.1016/S0008-6223(00)00242-6
Scott Kirkpatrick, Percolation and Conduction Reviews of Modern Physics. ,vol. 45, pp. 574- 588 ,(1973) , 10.1103/REVMODPHYS.45.574
D. Jeulin, L. Savary, Effective Complex Permittivity of Random Composites Journal De Physique I. ,vol. 7, pp. 1123- 1142 ,(1997) , 10.1051/JP1:1997103
Ravi Viswanathan, Michael B. Heaney, Direct imaging of the percolation network in a three-dimensional disordered conductor-insulator composite. Physical Review Letters. ,vol. 75, pp. 4433- 4436 ,(1995) , 10.1103/PHYSREVLETT.75.4433
I. Balberg, Limits on the continuum-percolation transport exponents Physical Review B. ,vol. 57, pp. 13351- 13354 ,(1998) , 10.1103/PHYSREVB.57.13351
F. Houzé, R. Meyer, O. Schneegans, L. Boyer, Imaging the local electrical properties of metal surfaces by atomic force microscopy with conducting probes Applied Physics Letters. ,vol. 69, pp. 1975- 1977 ,(1996) , 10.1063/1.117179
Laurent Lamaignère, François Carmona, Didier Sornette, Experimental Realization of Critical Thermal Fuse Rupture. Physical Review Letters. ,vol. 77, pp. 2738- 2741 ,(1996) , 10.1103/PHYSREVLETT.77.2738
Michael B. Heaney, Resistance‐expansion‐temperature behavior of a disordered conductor–insulator composite Applied Physics Letters. ,vol. 69, pp. 2602- 2604 ,(1996) , 10.1063/1.117713