Ligand-Controlled Formation of a Low-Valent Pincer Rhodium(I)-Dioxygen Adduct Bearing a Very Short O O Bond

作者: Christian M. Frech , Linda J. W. Shimon , David Milstein

DOI: 10.1002/HLCA.200690170

关键词: Oxygen transferTransition metal dioxygen complexChemistryMolecular oxygenMedicinal chemistryPincer movementAdductRhodiumLigandPhotochemistryPartial decomposition

摘要: … based on experimental and computational comparison of PNP and PCP IrIII systems [48]. … thiolate), where, additionally, incorporation of the CO group into the benzothiazole-2thiolate …

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