Hydrolysis reaction of ball-milled Mg-metal chlorides composite for hydrogen generation for fuel cells
作者： Shuang Wang , Li-Xian Sun , Fen Xu , Cheng-Li Jiao , Jian Zhang
DOI: 10.1016/J.IJHYDENE.2012.01.099
关键词: Ball mill 、 Composite number 、 Kinetics 、 Materials science 、 Single displacement reaction 、 Hydrolysis 、 Hydrogen fuel 、 Inorganic chemistry 、 Metal 、 Nuclear chemistry 、 Hydrogen production
摘要: In this paper, the hydrolysis properties for hydrogen generation by Mg-metal chlorides composites in pure water are investigated. The were prepared high energy ball milling. It is found that very promising reaction. micro-galvanic cell formed Mg and other metal which produced replacement reaction occurred during ball-milling process effective improving reactivity. Based on investigations of different kinds additives, it Mg-10 wt% FeCl3 composite ball-milled 30 min has best with an initial rate 1479.1 ml*g(-1) min(-1) a theoretical production yield 98% 2 min. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published Elsevier Ltd. All rights reserved.
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