Stereoselective Synthesis of Cyclic Ethers via the Palladium-Catalyzed Intramolecular Addition of Alcohols to Phosphono Allylic Carbonates

作者: Anyu He , Nongnuch Sutivisedsak , Christopher D Spilling , None

DOI: 10.1021/OL900980S

关键词: Intramolecular forceGrubbs' catalystAllyl compoundMetathesisAllylic rearrangementPalladiumChemistryOrganic chemistryIodideCatalysis

摘要: Cross metathesis of the acrolein-derived phosphono allylic carbonate and hydroxy alkenes using second generation Grubbs catalyst copper(I) iodide gave substituted phosphonates in good yield...

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